ACS Energy Letters, volume 4, issue 1, pages 265-270
Solvent-Engineered Design of Argyrodite Li6PS5X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity
Laidong Zhou
1
,
Kern Ho Park
1
,
Xiaoqi Sun
1
,
Fabien Lalère
1
,
Torben Adermann
2
,
Pascal Hartmann
2
,
Publication type: Journal Article
Publication date: 2018-11-20
Journal:
ACS Energy Letters
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 22
ISSN: 23808195, 23808195
Materials Chemistry
Chemistry (miscellaneous)
Energy Engineering and Power Technology
Fuel Technology
Renewable Energy, Sustainability and the Environment
Abstract
Argyrodites, Li6PS5X (X = Cl, Br), are considered to be one of the most promising solid-state electrolytes for solid-state batteries. However, while traditional ball-mill approaches to prepare these materials do not promote scale-up, solution-based preparative methods have resulted in poor ionic conductivity. Herein, we report a solution-engineered, scalable approach to these materials, including the new argyrodite solid solution phase Li6–yPS5–yCl1+y (y = 0–0.5), that shows very high ionic conductivities (up to 3.9 mS·cm–1) and negligible electronic conductivities. These properties are almost the same as their analogues prepared by solid-state methods, owing to a lack of amorphous contributions and low impurity contents ranging from 3 to 10%. Electrochemical performance is demonstrated for Li6PS5Cl in a prototype solid-state battery and compared to that of the same solid electrolyte derived from classic ball-milling processing.
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Citations by publishers
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- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Zhou L. et al. Solvent-Engineered Design of Argyrodite Li6PS5X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity // ACS Energy Letters. 2018. Vol. 4. No. 1. pp. 265-270.
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Zhou L., Park K. H., Sun X., Lalère F., Adermann T., Hartmann P., Nazar L. F. Solvent-Engineered Design of Argyrodite Li6PS5X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity // ACS Energy Letters. 2018. Vol. 4. No. 1. pp. 265-270.
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TY - JOUR
DO - 10.1021/acsenergylett.8b01997
UR - https://doi.org/10.1021/acsenergylett.8b01997
TI - Solvent-Engineered Design of Argyrodite Li6PS5X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity
T2 - ACS Energy Letters
AU - Lalère, Fabien
AU - Adermann, Torben
AU - Hartmann, Pascal
AU - Zhou, Laidong
AU - Nazar, Linda F.
AU - Park, Kern Ho
AU - Sun, Xiaoqi
PY - 2018
DA - 2018/11/20 00:00:00
PB - American Chemical Society (ACS)
SP - 265-270
IS - 1
VL - 4
SN - 2380-8195
SN - 2380-8195
ER -
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@article{2018_Zhou,
author = {Fabien Lalère and Torben Adermann and Pascal Hartmann and Laidong Zhou and Linda F. Nazar and Kern Ho Park and Xiaoqi Sun},
title = {Solvent-Engineered Design of Argyrodite Li6PS5X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity},
journal = {ACS Energy Letters},
year = {2018},
volume = {4},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acsenergylett.8b01997},
number = {1},
pages = {265--270},
doi = {10.1021/acsenergylett.8b01997}
}
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Zhou, Laidong, et al. “Solvent-Engineered Design of Argyrodite Li6PS5X (X = Cl, Br, I) Solid Electrolytes with High Ionic Conductivity.” ACS Energy Letters, vol. 4, no. 1, Nov. 2018, pp. 265-270. https://doi.org/10.1021/acsenergylett.8b01997.
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