ACS Nano, volume 16, issue 4, pages 6002-6012
“Missing” One-Dimensional Red-Phosphorus Chains Encapsulated within Single-Walled Carbon Nanotubes
Rybkovskiy Dmitry V.
1, 2
,
Koroteev V. O.
3
,
Impellizzeri A.
4
,
Vorfolomeeva A A
5
,
Gerasimov Evgeny
6
,
Okotrub A. V.
5
,
Chuvilin A
3, 7
,
3
CIC NanoGUNE BRTA, Tolosa Hiribidea 76, E-20018 Donostia, San Sebastian, Spain
|
Publication type: Journal Article
Publication date: 2022-04-04
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
We identify the "missing" 1D-phosphorus allotrope, red phosphorus chains, formed in the interior of tip-opened single-walled carbon nanotubes (SWCNTs). Via a comprehensive experimental and theoretical study we show that in intermediate diameter cavities (1.6-2.9 nm), phosphorus vapor condenses into linear P8]P2 chains and fibrous red-phosphorus type cross-linked double-chains. Thermogravimetric and X-ray photoelectron spectroscopy analysis estimates ∼7 atom % of elemental phosphorus in the sample, while high-resolution energy dispersive X-ray spectroscopy mapping reveals that phosphorus fills the SWCNTs. High-resolution transmission electron microscopy (HRTEM) shows long chains inside the nanotubes with varying arrangement and packing density. A detailed match is obtained between density functional theory (DFT) simulations, HRTEM, and low-frequency Raman spectroscopy. Notably, a signature spectroscopic signal for phosphorus chain cross-linking is identified. When coupled with reinterpretation of literature data and wide-ranging DFT calculations, these results reveal a comprehensive picture of the diameter dependence of confined 1D-phosphorus allotropes.
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1 publication, 7.14%
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1 publication, 7.14%
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1
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Citations by publishers
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1
2
3
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Royal Society of Chemistry (RSC)
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3 publications, 21.43%
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Springer Nature
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3 publications, 21.43%
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American Chemical Society (ACS)
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2 publications, 14.29%
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Pleiades Publishing
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Pleiades Publishing
2 publications, 14.29%
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Wiley
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Wiley
2 publications, 14.29%
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Multidisciplinary Digital Publishing Institute (MDPI)
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 7.14%
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Elsevier
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Elsevier
1 publication, 7.14%
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1
2
3
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Rybkovskiy D. V. et al. “Missing” One-Dimensional Red-Phosphorus Chains Encapsulated within Single-Walled Carbon Nanotubes // ACS Nano. 2022. Vol. 16. No. 4. pp. 6002-6012.
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Rybkovskiy D. V., Koroteev V. O., Impellizzeri A., Vorfolomeeva A. A., Gerasimov E., Okotrub A. V., Chuvilin A., Bulusheva L. G., Ewels C. “Missing” One-Dimensional Red-Phosphorus Chains Encapsulated within Single-Walled Carbon Nanotubes // ACS Nano. 2022. Vol. 16. No. 4. pp. 6002-6012.
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TY - JOUR
DO - 10.1021/acsnano.1c11349
UR - https://doi.org/10.1021%2Facsnano.1c11349
TI - “Missing” One-Dimensional Red-Phosphorus Chains Encapsulated within Single-Walled Carbon Nanotubes
T2 - ACS Nano
AU - Impellizzeri, A.
AU - Okotrub, A. V.
AU - Chuvilin, A
AU - Rybkovskiy, Dmitry V.
AU - Koroteev, V. O.
AU - Vorfolomeeva, A A
AU - Gerasimov, Evgeny
AU - Bulusheva, Lyubov G.
AU - Ewels, Chris
PY - 2022
DA - 2022/04/04 00:00:00
PB - American Chemical Society (ACS)
SP - 6002-6012
IS - 4
VL - 16
SN - 1936-0851
SN - 1936-086X
ER -
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@article{2022_Rybkovskiy,
author = {A. Impellizzeri and A. V. Okotrub and A Chuvilin and Dmitry V. Rybkovskiy and V. O. Koroteev and A A Vorfolomeeva and Evgeny Gerasimov and Lyubov G. Bulusheva and Chris Ewels},
title = {“Missing” One-Dimensional Red-Phosphorus Chains Encapsulated within Single-Walled Carbon Nanotubes},
journal = {ACS Nano},
year = {2022},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {apr},
url = {https://doi.org/10.1021%2Facsnano.1c11349},
number = {4},
pages = {6002--6012},
doi = {10.1021/acsnano.1c11349}
}
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Rybkovskiy, Dmitry V., et al. ““Missing” One-Dimensional Red-Phosphorus Chains Encapsulated within Single-Walled Carbon Nanotubes.” ACS Nano, vol. 16, no. 4, Apr. 2022, pp. 6002-6012. https://doi.org/10.1021%2Facsnano.1c11349.