ACS Nano, volume 9, issue 4, pages 4277-4287
Temperature Dependence of Interband Transitions in Wurtzite InP Nanowires
Attilio Zilli
1
,
Marta De Luca
1
,
D. Tedeschi
1
,
H. Aruni Fonseka
2
,
Antonio Miriametro
1
,
H. H. Tan
2
,
Chennupati Jagadish
2
,
Mario Capizzi
1
,
Antonio Polimeni
1
Publication type: Journal Article
Publication date: 2015-03-31
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
Semiconductor nanowires (NWs) formed by non-nitride III–V compounds grow preferentially with wurtzite (WZ) lattice. This is contrary to bulk and two-dimensional layers of the same compounds, where only zincblende (ZB) is observed. The absorption spectrum of WZ materials differs largely from their ZB counterparts and shows three transitions, referred to as A, B, and C in order of increasing energy, involving the minimum of the conduction band and different critical points of the valence band. In this work, we determine the temperature dependence (T = 10–310 K) of the energy of transitions A, B, and C in ensembles of WZ InP NWs by photoluminescence (PL) and PL excitation (PLE) spectroscopy. For the whole temperature and energy ranges investigated, the PL and PLE spectra are quantitatively reproduced by a theoretical model taking into account contribution from both exciton and continuum states. WZ InP is found to behave very similarly to wide band gap III-nitrides and II–VI compounds, where the energy of A, B, and C displays the same temperature dependence. This finding unveils a general feature of the thermal properties of WZ materials that holds regardless of the bond polarity and energy gap of the crystal. Furthermore, no differences are observed in the temperature dependence of the fundamental band gap energy in WZ InP NWs and ZB InP (both NWs and bulk). This result points to a negligible role played by the WZ/ZB differences in determining the deformation potentials and the extent of the electron–phonon interaction that is a direct consequence of the similar nearest neighbor arrangement in the two lattices.
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- We do not take into account publications without a DOI.
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Zilli A. et al. Temperature Dependence of Interband Transitions in Wurtzite InP Nanowires // ACS Nano. 2015. Vol. 9. No. 4. pp. 4277-4287.
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Zilli A., De Luca M., Tedeschi D., Fonseka H. A., Miriametro A., Tan H. H., Jagadish C., Capizzi M., Polimeni A. Temperature Dependence of Interband Transitions in Wurtzite InP Nanowires // ACS Nano. 2015. Vol. 9. No. 4. pp. 4277-4287.
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TY - JOUR
DO - 10.1021/acsnano.5b00699
UR - https://doi.org/10.1021/acsnano.5b00699
TI - Temperature Dependence of Interband Transitions in Wurtzite InP Nanowires
T2 - ACS Nano
AU - Miriametro, Antonio
AU - Zilli, Attilio
AU - De Luca, Marta
AU - Tedeschi, D.
AU - Fonseka, H. Aruni
AU - Tan, H. H.
AU - Jagadish, Chennupati
AU - Capizzi, Mario
AU - Polimeni, Antonio
PY - 2015
DA - 2015/03/31 00:00:00
PB - American Chemical Society (ACS)
SP - 4277-4287
IS - 4
VL - 9
SN - 1936-0851
SN - 1936-086X
ER -
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@article{2015_Zilli,
author = {Antonio Miriametro and Attilio Zilli and Marta De Luca and D. Tedeschi and H. Aruni Fonseka and H. H. Tan and Chennupati Jagadish and Mario Capizzi and Antonio Polimeni},
title = {Temperature Dependence of Interband Transitions in Wurtzite InP Nanowires},
journal = {ACS Nano},
year = {2015},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acsnano.5b00699},
number = {4},
pages = {4277--4287},
doi = {10.1021/acsnano.5b00699}
}
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MLA
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Zilli, Attilio, et al. “Temperature Dependence of Interband Transitions in Wurtzite InP Nanowires.” ACS Nano, vol. 9, no. 4, Mar. 2015, pp. 4277-4287. https://doi.org/10.1021/acsnano.5b00699.