Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces
Publication type: Journal Article
Publication date: 2015-06-11
scimago Q1
wos Q1
SJR: 4.497
CiteScore: 24.2
Impact factor: 16.0
ISSN: 19360851, 1936086X
PubMed ID:
26039934
General Physics and Astronomy
General Materials Science
General Engineering
Abstract
Soft or "liquid-liquid" interfaces were functionalized by roughly half a monolayer of mirror-like nanofilms of gold nanoparticles using a precise interfacial microinjection method. The surface coverage of the nanofilm was characterized by ion transfer voltammetry. These gold nanoparticle films represent an ideal model system for studying both the thermodynamic and kinetic aspects of interfacial redox catalysis. The electric polarization of these soft interfaces is easily controllable, and thus the Fermi level of the electrons in the interfacial gold nanoparticle film can be easily manipulated. Here, we study interfacial redox catalysis between two redox couples located in adjacent immiscible phases and highlight the catalytic properties of a gold nanoparticle film toward heterogeneous electron transfer reactions.
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Metrics
83
Total citations:
83
Citations from 2024:
12
(14.46%)
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MLA
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GOST
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Smirnov E. A. et al. Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces // ACS Nano. 2015. Vol. 9. No. 6. pp. 6565-6575.
GOST all authors (up to 50)
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Smirnov E. A., Peljo P., Scanlon M. D., Girault H. Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces // ACS Nano. 2015. Vol. 9. No. 6. pp. 6565-6575.
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RIS
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TY - JOUR
DO - 10.1021/acsnano.5b02547
UR - https://doi.org/10.1021/acsnano.5b02547
TI - Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces
T2 - ACS Nano
AU - Smirnov, Evgeny A.
AU - Peljo, Pekka
AU - Scanlon, Micheál D.
AU - Girault, Hubert
PY - 2015
DA - 2015/06/11
PB - American Chemical Society (ACS)
SP - 6565-6575
IS - 6
VL - 9
PMID - 26039934
SN - 1936-0851
SN - 1936-086X
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2015_Smirnov,
author = {Evgeny A. Smirnov and Pekka Peljo and Micheál D. Scanlon and Hubert Girault},
title = {Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces},
journal = {ACS Nano},
year = {2015},
volume = {9},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/acsnano.5b02547},
number = {6},
pages = {6565--6575},
doi = {10.1021/acsnano.5b02547}
}
Cite this
MLA
Copy
Smirnov, Evgeny A., et al. “Interfacial Redox Catalysis on Gold Nanofilms at Soft Interfaces.” ACS Nano, vol. 9, no. 6, Jun. 2015, pp. 6565-6575. https://doi.org/10.1021/acsnano.5b02547.
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