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volume 5 issue 14 pages 8200-8210

Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization

Yuriy A Kvashnin 1
Oleg S Eltsov 2
Alexey Tameev 1, 3
Gennady L. Rusinov 1, 2
O. N. Chupakhin 1, 2
Valery N. Charushin 1, 2
Publication typeJournal Article
Publication date2020-03-30
scimago Q1
wos Q2
SJR0.773
CiteScore7.1
Impact factor4.3
ISSN24701343
General Chemistry
General Chemical Engineering
Abstract
Herein, we describe the synthesis of unsymmetrically substituted dibenzo[f,h]furazano[3,4-b]quinoxalines by intramolecular cyclization through direct transition metal-free C–H functionalization. The electrochemical and photophysical properties for several polycycles have been measured. In thin films of the dibenzo[f,h]furazano[3,4-b]quinoxalines, hole mobility is in the order of 10–4 cm2 V–1 s–1. The results show that the HOMO and LUMO energy levels are appropriate for using the compounds as hole-transport materials in thin-film devices, in particular, organic and perovskite solar cells.
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GOST |
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Kvashnin Y. A. et al. Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization // ACS Omega. 2020. Vol. 5. No. 14. pp. 8200-8210.
GOST all authors (up to 50) Copy
Kvashnin Y. A., Verbitskiy E. V., Eltsov O. S., Slepukhin P. A., Tameev A., Nekrasova N. V., Rusinov G. L., Nunzi J., Chupakhin O. N., Charushin V. N. Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization // ACS Omega. 2020. Vol. 5. No. 14. pp. 8200-8210.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsomega.0c00479
UR - https://doi.org/10.1021/acsomega.0c00479
TI - Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization
T2 - ACS Omega
AU - Kvashnin, Yuriy A
AU - Verbitskiy, Egor V
AU - Eltsov, Oleg S
AU - Slepukhin, Pavel A.
AU - Tameev, Alexey
AU - Nekrasova, N V
AU - Rusinov, Gennady L.
AU - Nunzi, Jean-Michel
AU - Chupakhin, O. N.
AU - Charushin, Valery N.
PY - 2020
DA - 2020/03/30
PB - American Chemical Society (ACS)
SP - 8200-8210
IS - 14
VL - 5
PMID - 32309730
SN - 2470-1343
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{2020_Kvashnin,
author = {Yuriy A Kvashnin and Egor V Verbitskiy and Oleg S Eltsov and Pavel A. Slepukhin and Alexey Tameev and N V Nekrasova and Gennady L. Rusinov and Jean-Michel Nunzi and O. N. Chupakhin and Valery N. Charushin},
title = {Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization},
journal = {ACS Omega},
year = {2020},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/acsomega.0c00479},
number = {14},
pages = {8200--8210},
doi = {10.1021/acsomega.0c00479}
}
MLA
Cite this
MLA Copy
Kvashnin, Yuriy A., et al. “Dibenzo[f,h]furazano[3,4-b]quinoxalines: Synthesis by Intramolecular Cyclization through Direct Transition Metal-Free C–H Functionalization and Electrochemical, Photophysical, and Charge Mobility Characterization.” ACS Omega, vol. 5, no. 14, Mar. 2020, pp. 8200-8210. https://doi.org/10.1021/acsomega.0c00479.
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