Open Access
ACS Omega, volume 6, issue 27, pages 17267-17275
Biocompatible pH-Degradable Functional Capsules Based on Melamine Cyanurate Self-Assembly
Imoro Nfayem
1
,
Nesterov Sergey
1
,
Timralieva Alexandra A.
1
,
Gets Dmitry
1
,
Nebalueva Anna
1
,
Kondratyuk Nikolay D.
2, 3
,
Orekhov Nikita D.
2, 3, 4
,
Publication type: Journal Article
Publication date: 2021-06-25
PubMed ID:
34278113
General Chemistry
General Chemical Engineering
Abstract
Development of adaptive self-regulating materials and chemical–biological systems—self-healing, self-regulating, etc.—is an advanced modern trend. The very sensitive pH-controlled functionality of supramolecular assemblies is a very useful tool for chemical and biochemical implementations. However, the assembly process can be tuned by various factors that can be used for both better functionality control and further functionalization such as active species, e.g., drugs and dyes, and encapsulation. Here, the effect of a dye, sodium fluorescein (uranine) (FL), on the formation of a self-assembled melamine cyanurate (M–CA) structure is investigated and calculated with density functional theory (DFT) and molecular dynamics. Interestingly, the dye greatly affects the self-assembly process at early stages from the formation of dimers, trimers, and tetramer to nucleation control. The supramolecular structure disassembly and subsequent release of trapped dye occurred under both high- and low-pH conditions. This system can be used for time-prolonged bacterial staining and development of supramolecular capsules for the system chemistry approach.
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Citations by publishers
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1 publication, 12.5%
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1 publication, 12.5%
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Imoro N. et al. Biocompatible pH-Degradable Functional Capsules Based on Melamine Cyanurate Self-Assembly // ACS Omega. 2021. Vol. 6. No. 27. pp. 17267-17275.
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Imoro N., Shilovskikh V. V., Nesterov S., Timralieva A. A., Gets D., Nebalueva A., Lavrentev F. V., Novikov A. S., Kondratyuk N. D., Orekhov N. D., Skorb E. V. Biocompatible pH-Degradable Functional Capsules Based on Melamine Cyanurate Self-Assembly // ACS Omega. 2021. Vol. 6. No. 27. pp. 17267-17275.
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TY - JOUR
DO - 10.1021/acsomega.1c01124
UR - https://doi.org/10.1021%2Facsomega.1c01124
TI - Biocompatible pH-Degradable Functional Capsules Based on Melamine Cyanurate Self-Assembly
T2 - ACS Omega
AU - Imoro, Nfayem
AU - Timralieva, Alexandra A.
AU - Nebalueva, Anna
AU - Gets, Dmitry
AU - Skorb, Ekaterina V.
AU - Shilovskikh, Vladimir V.
AU - Nesterov, Sergey
AU - Lavrentev, Filipp V
AU - Novikov, Alexander S.
AU - Kondratyuk, Nikolay D.
AU - Orekhov, Nikita D.
PY - 2021
DA - 2021/06/25 00:00:00
PB - American Chemical Society (ACS)
SP - 17267-17275
IS - 27
VL - 6
PMID - 34278113
SN - 2470-1343
ER -
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@article{2021_Imoro,
author = {Nfayem Imoro and Alexandra A. Timralieva and Anna Nebalueva and Dmitry Gets and Ekaterina V. Skorb and Vladimir V. Shilovskikh and Sergey Nesterov and Filipp V Lavrentev and Alexander S. Novikov and Nikolay D. Kondratyuk and Nikita D. Orekhov},
title = {Biocompatible pH-Degradable Functional Capsules Based on Melamine Cyanurate Self-Assembly},
journal = {ACS Omega},
year = {2021},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021%2Facsomega.1c01124},
number = {27},
pages = {17267--17275},
doi = {10.1021/acsomega.1c01124}
}
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MLA
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Imoro, Nfayem, et al. “Biocompatible pH-Degradable Functional Capsules Based on Melamine Cyanurate Self-Assembly.” ACS Omega, vol. 6, no. 27, Jun. 2021, pp. 17267-17275. https://doi.org/10.1021%2Facsomega.1c01124.