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Cobalt(I)-Catalyzed [6π + 2π] Cycloaddition of 1,2-Dienes and 1,3-Diynes to N-Carbocholesteroxyazepine in the Synthesis of Previously Undescribed Heterofunctional 9-Azabicyclo[4.2.1]nonadi(tri)enes
Publication type: Journal Article
Publication date: 2021-08-12
scimago Q1
wos Q2
SJR: 0.773
CiteScore: 7.1
Impact factor: 4.3
ISSN: 24701343
PubMed ID:
34471777
General Chemistry
General Chemical Engineering
Abstract
Promising heterofunctional (E)-9-azabicyclo[4.2.1]nona-2,4-dienes (79–92%) and 9-azabicyclo[4.2.1]nona-2,4,7-trienes (77–90%) containing a cholesterol fragment in the structure have been synthesized for the first time through the [6π + 2π] cycloaddition reaction of terminal 1,2-dienes and symmetric 1,3-diynes with N-carbocholesteroxyazepine under the action of the Co(acac)2(dppe)/Zn/ZnI2 three-component catalytic system.
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Kadikova G. N., D'yakonov V. A., Dzhemilev U. M. Cobalt(I)-Catalyzed [6π + 2π] Cycloaddition of 1,2-Dienes and 1,3-Diynes to N-Carbocholesteroxyazepine in the Synthesis of Previously Undescribed Heterofunctional 9-Azabicyclo[4.2.1]nonadi(tri)enes // ACS Omega. 2021. Vol. 6. No. 33. pp. 21755-21763.
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Kadikova G. N., D'yakonov V. A., Dzhemilev U. M. Cobalt(I)-Catalyzed [6π + 2π] Cycloaddition of 1,2-Dienes and 1,3-Diynes to N-Carbocholesteroxyazepine in the Synthesis of Previously Undescribed Heterofunctional 9-Azabicyclo[4.2.1]nonadi(tri)enes // ACS Omega. 2021. Vol. 6. No. 33. pp. 21755-21763.
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TY - JOUR
DO - 10.1021/acsomega.1c03321
UR - https://doi.org/10.1021/acsomega.1c03321
TI - Cobalt(I)-Catalyzed [6π + 2π] Cycloaddition of 1,2-Dienes and 1,3-Diynes to N-Carbocholesteroxyazepine in the Synthesis of Previously Undescribed Heterofunctional 9-Azabicyclo[4.2.1]nonadi(tri)enes
T2 - ACS Omega
AU - Kadikova, Gulnara N.
AU - D'yakonov, Vladimir A
AU - Dzhemilev, Usein M
PY - 2021
DA - 2021/08/12
PB - American Chemical Society (ACS)
SP - 21755-21763
IS - 33
VL - 6
PMID - 34471777
SN - 2470-1343
ER -
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@article{2021_Kadikova,
author = {Gulnara N. Kadikova and Vladimir A D'yakonov and Usein M Dzhemilev},
title = {Cobalt(I)-Catalyzed [6π + 2π] Cycloaddition of 1,2-Dienes and 1,3-Diynes to N-Carbocholesteroxyazepine in the Synthesis of Previously Undescribed Heterofunctional 9-Azabicyclo[4.2.1]nonadi(tri)enes},
journal = {ACS Omega},
year = {2021},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acsomega.1c03321},
number = {33},
pages = {21755--21763},
doi = {10.1021/acsomega.1c03321}
}
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MLA
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Kadikova, Gulnara N., et al. “Cobalt(I)-Catalyzed [6π + 2π] Cycloaddition of 1,2-Dienes and 1,3-Diynes to N-Carbocholesteroxyazepine in the Synthesis of Previously Undescribed Heterofunctional 9-Azabicyclo[4.2.1]nonadi(tri)enes.” ACS Omega, vol. 6, no. 33, Aug. 2021, pp. 21755-21763. https://doi.org/10.1021/acsomega.1c03321.