Open Access
Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties
Тип публикации: Journal Article
Дата публикации: 2022-07-13
scimago Q1
wos Q2
БС1
SJR: 0.773
CiteScore: 7.1
Impact factor: 4.3
ISSN: 24701343
PubMed ID:
35910108
General Chemistry
General Chemical Engineering
Краткое описание
We have achieved the first series of DAAQ-based building blocks, viz., n-TIPS-DAAQs (n = 1-4), and unraveled a rational design of their π-extension. Sequentially increasing numbers (n) of the exocyclic π-linkers showed (a) a systematic bathochromic shift in both absorption and emission spectra, (b) selective stabilization of the lowest-unoccupied molecular orbital (LUMO), and (c) unselective changes in the S0/S1 states. To our surprise, the LUMO level of 4-TIPS-DAAQ (-3.72 eV) was found to be comparable to that of PC60BM.
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ГОСТ
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Masilamani G. et al. Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties // ACS Omega. 2022. Vol. 7. No. 29. pp. 25874-25880.
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Masilamani G., Batchu H., Amsallem D., Bedi A. Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties // ACS Omega. 2022. Vol. 7. No. 29. pp. 25874-25880.
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TY - JOUR
DO - 10.1021/acsomega.2c03609
UR - https://doi.org/10.1021/acsomega.2c03609
TI - Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties
T2 - ACS Omega
AU - Masilamani, Ganesh
AU - Batchu, Harikrishna
AU - Amsallem, Dana
AU - Bedi, Anjan
PY - 2022
DA - 2022/07/13
PB - American Chemical Society (ACS)
SP - 25874-25880
IS - 29
VL - 7
PMID - 35910108
SN - 2470-1343
ER -
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@article{2022_Masilamani,
author = {Ganesh Masilamani and Harikrishna Batchu and Dana Amsallem and Anjan Bedi},
title = {Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties},
journal = {ACS Omega},
year = {2022},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acsomega.2c03609},
number = {29},
pages = {25874--25880},
doi = {10.1021/acsomega.2c03609}
}
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MLA
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Masilamani, Ganesh, et al. “Novel Series of Diaminoanthraquinone-Based π-Extendable Building Blocks with Tunable Optoelectronic Properties.” ACS Omega, vol. 7, no. 29, Jul. 2022, pp. 25874-25880. https://doi.org/10.1021/acsomega.2c03609.