Open Access
Open access
том 7 издание 36 страницы 32562-32568

Stereoselective Synthesis of Benzo[a]quinolizidines via Aerobic DDQ-Catalyzed Allylation and Reductive Cyclization

Тип публикацииJournal Article
Дата публикации2022-08-31
scimago Q1
wos Q2
БС1
SJR0.773
CiteScore7.1
Impact factor4.3
ISSN24701343
General Chemistry
General Chemical Engineering
Краткое описание
Stereoselective synthesis of C4-substituted benzo[a]quinolizidines via redox-controlled catalytic C-C-bond-forming reactions was carried out. Aerobic DDQ-catalyzed allylation of N-Cbz tetrahydroisoquinolines efficiently provided α-allylated products 5, which were transformed to enones 6 via cross-metathesis reactions using the second-generation Hoveyda-Grubbs catalyst. Palladium-catalyzed hydrogenation of 6 prompted alkene reduction, protecting group removal, and intramolecular reductive amination in one step to afford the desired benzo[a]quinolizidines 7 as single diastereomers.
Найдено 
Найдено 

Топ-30

Журналы

1
Progress in Heterocyclic Chemistry
1 публикация, 20%
Russian Chemical Reviews
1 публикация, 20%
RSC Advances
1 публикация, 20%
ChemistryOpen
1 публикация, 20%
1

Издатели

1
2
Elsevier
2 публикации, 40%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 публикация, 20%
Royal Society of Chemistry (RSC)
1 публикация, 20%
Wiley
1 публикация, 20%
1
2
  • Мы не учитываем публикации, у которых нет DOI.
  • Статистика публикаций обновляется еженедельно.

Вы ученый?

Создайте профиль, чтобы получать персональные рекомендации коллег, конференций и новых статей.
Метрики
5
Поделиться
Цитировать
ГОСТ |
Цитировать
Jung S. et al. Stereoselective Synthesis of Benzo[a]quinolizidines via Aerobic DDQ-Catalyzed Allylation and Reductive Cyclization // ACS Omega. 2022. Vol. 7. No. 36. pp. 32562-32568.
ГОСТ со всеми авторами (до 50) Скопировать
Jung S., Yoon S., Lee J. K., Min S. Stereoselective Synthesis of Benzo[a]quinolizidines via Aerobic DDQ-Catalyzed Allylation and Reductive Cyclization // ACS Omega. 2022. Vol. 7. No. 36. pp. 32562-32568.
RIS |
Цитировать
TY - JOUR
DO - 10.1021/acsomega.2c04154
UR - https://doi.org/10.1021/acsomega.2c04154
TI - Stereoselective Synthesis of Benzo[a]quinolizidines via Aerobic DDQ-Catalyzed Allylation and Reductive Cyclization
T2 - ACS Omega
AU - Jung, Sunhwa
AU - Yoon, Seungri
AU - Lee, Jae Kyun
AU - Min, Sun-Joon
PY - 2022
DA - 2022/08/31
PB - American Chemical Society (ACS)
SP - 32562-32568
IS - 36
VL - 7
PMID - 36120044
SN - 2470-1343
ER -
BibTex |
Цитировать
BibTex (до 50 авторов) Скопировать
@article{2022_Jung,
author = {Sunhwa Jung and Seungri Yoon and Jae Kyun Lee and Sun-Joon Min},
title = {Stereoselective Synthesis of Benzo[a]quinolizidines via Aerobic DDQ-Catalyzed Allylation and Reductive Cyclization},
journal = {ACS Omega},
year = {2022},
volume = {7},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/acsomega.2c04154},
number = {36},
pages = {32562--32568},
doi = {10.1021/acsomega.2c04154}
}
MLA
Цитировать
Jung, Sunhwa, et al. “Stereoselective Synthesis of Benzo[a]quinolizidines via Aerobic DDQ-Catalyzed Allylation and Reductive Cyclization.” ACS Omega, vol. 7, no. 36, Aug. 2022, pp. 32562-32568. https://doi.org/10.1021/acsomega.2c04154.