Open Access
ACS Omega, volume 1, issue 5, pages 854-867
Copper-Bispidine Complexes: Synthesis and Complex Stability Study
Medved'ko Aleksei V.
1
,
Egorova B. V.
1
,
Komarova Alina A
1
,
Rakhimov Rustem D
1
,
Krutko Dmitri P
1
,
Publication type: Journal Article
Publication date: 2016-11-08
PubMed ID:
31457168
General Chemistry
General Chemical Engineering
Abstract
A new series of dicarboxylic derivatives of bispidines have been synthesized to develop novel copper(II) complexes suitable as imaging agents for positron emission tomography. For characterization purposes, copper complexes of bispidines were synthesized in the pure form and in quantitative yields by neutralization of ligands with malachite. The formation of complexes and their stoichiometries were studied by potentiometric titration, cyclic voltammetry, and spectroscopic methods. The stability constants were found to be fairly suitable for copper cation fixation inside dianionic chelate molecules.
Citations by journals
|
1
2
|
|
|
Russian Journal of Organic Chemistry
|
Russian Journal of Organic Chemistry
2 publications, 9.52%
|
|
Russian Chemical Bulletin
|
Russian Chemical Bulletin
2 publications, 9.52%
|
|
Mendeleev Communications
|
Mendeleev Communications
2 publications, 9.52%
|
|
Nanomaterials
|
Nanomaterials
1 publication, 4.76%
|
|
Journal of Organometallic Chemistry
|
Journal of Organometallic Chemistry
1 publication, 4.76%
|
|
CrystEngComm
|
CrystEngComm
1 publication, 4.76%
|
|
Russian Chemical Reviews
|
Russian Chemical Reviews
1 publication, 4.76%
|
|
ACS Medicinal Chemistry Letters
|
ACS Medicinal Chemistry Letters
1 publication, 4.76%
|
|
Chemistry of Heterocyclic Compounds
|
Chemistry of Heterocyclic Compounds
1 publication, 4.76%
|
|
Acta Crystallographica Section E: Crystallographic Communications
|
Acta Crystallographica Section E: Crystallographic Communications
1 publication, 4.76%
|
|
Molecules
|
Molecules
1 publication, 4.76%
|
|
Tetrahedron Letters
|
Tetrahedron Letters
1 publication, 4.76%
|
|
Inorganica Chimica Acta
|
Inorganica Chimica Acta
1 publication, 4.76%
|
|
ChemPlusChem
|
ChemPlusChem
1 publication, 4.76%
|
|
Journal of Labelled Compounds and Radiopharmaceuticals
|
Journal of Labelled Compounds and Radiopharmaceuticals
1 publication, 4.76%
|
|
Dalton Transactions
|
Dalton Transactions
1 publication, 4.76%
|
|
Journal of Organic Chemistry
|
Journal of Organic Chemistry
1 publication, 4.76%
|
|
1
2
|
Citations by publishers
|
1
2
3
4
5
|
|
|
Elsevier
|
Elsevier
5 publications, 23.81%
|
|
Springer Nature
|
Springer Nature
3 publications, 14.29%
|
|
Multidisciplinary Digital Publishing Institute (MDPI)
|
Multidisciplinary Digital Publishing Institute (MDPI)
2 publications, 9.52%
|
|
Pleiades Publishing
|
Pleiades Publishing
2 publications, 9.52%
|
|
Royal Society of Chemistry (RSC)
|
Royal Society of Chemistry (RSC)
2 publications, 9.52%
|
|
American Chemical Society (ACS)
|
American Chemical Society (ACS)
2 publications, 9.52%
|
|
Wiley
|
Wiley
2 publications, 9.52%
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 4.76%
|
|
International Union of Crystallography (IUCr)
|
International Union of Crystallography (IUCr)
1 publication, 4.76%
|
|
1
2
3
4
5
|
- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2017,2018,2019,2020,2021,2022,2023],"ids":[0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0],"imageUrls":["","","","","","",""],"datasets":[{"label":"Citations number","data":[2,4,2,1,7,2,3],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["9.52","19.05","9.52","4.76","33.33","9.52","14.29"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Russian Journal of Organic Chemistry","Russian Chemical Bulletin","Mendeleev Communications","Nanomaterials","Journal of Organometallic Chemistry","CrystEngComm","Russian Chemical Reviews","ACS Medicinal Chemistry Letters","Chemistry of Heterocyclic Compounds","Acta Crystallographica Section E: Crystallographic Communications","Molecules","Tetrahedron Letters","Inorganica Chimica Acta","ChemPlusChem","Journal of Labelled Compounds and Radiopharmaceuticals","Dalton Transactions","Journal of Organic Chemistry"],"ids":[5728,10918,5294,10051,11834,7359,23802,360,16828,7164,1770,6133,1406,21067,174,8473,8697],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/xG3oC19920mmFVqkoVEGKGaMCeoalzyvWxPkVox5_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp"],"datasets":[{"label":"","data":[2,2,2,1,1,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[9.52,9.52,9.52,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76,4.76],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["Elsevier","Springer Nature","Multidisciplinary Digital Publishing Institute (MDPI)","Pleiades Publishing","Royal Society of Chemistry (RSC)","American Chemical Society (ACS)","Wiley","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii","International Union of Crystallography (IUCr)"],"ids":[17,8,202,101,123,40,11,9422,730],"codes":[0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/voXLqlsvTwv5p3iMQ8Dhs95nqB4AXOG7Taj7G4ra_medium.webp","\/storage\/images\/resized\/MjH1ITP7lMYGxeqUZfkt2BnVLgjkk413jwBV97XX_medium.webp","\/storage\/images\/resized\/oZgeErrVFhuDksyqFURLvYS1wtVSBWczh001igGo_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp","\/storage\/images\/resized\/xG3oC19920mmFVqkoVEGKGaMCeoalzyvWxPkVox5_medium.webp"],"datasets":[{"label":"","data":[5,3,2,2,2,2,2,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[23.81,14.29,9.52,9.52,9.52,9.52,9.52,4.76,4.76],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"}},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"}}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Medved'ko A. V. et al. Copper-Bispidine Complexes: Synthesis and Complex Stability Study // ACS Omega. 2016. Vol. 1. No. 5. pp. 854-867.
GOST all authors (up to 50)
Copy
Medved'ko A. V., Egorova B. V., Komarova A. A., Rakhimov R. D., Krutko D. P., Kalmykov S. N., Vatsadze S. Z. Copper-Bispidine Complexes: Synthesis and Complex Stability Study // ACS Omega. 2016. Vol. 1. No. 5. pp. 854-867.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acsomega.6b00237
UR - https://doi.org/10.1021%2Facsomega.6b00237
TI - Copper-Bispidine Complexes: Synthesis and Complex Stability Study
T2 - ACS Omega
AU - Medved'ko, Aleksei V.
AU - Komarova, Alina A
AU - Rakhimov, Rustem D
AU - Krutko, Dmitri P
AU - Egorova, B. V.
AU - Kalmykov, Stepan N.
AU - Vatsadze, Sergey Z.
PY - 2016
DA - 2016/11/08 00:00:00
PB - American Chemical Society (ACS)
SP - 854-867
IS - 5
VL - 1
PMID - 31457168
SN - 2470-1343
ER -
Cite this
BibTex
Copy
@article{2016_Medved'ko,
author = {Aleksei V. Medved'ko and Alina A Komarova and Rustem D Rakhimov and Dmitri P Krutko and B. V. Egorova and Stepan N. Kalmykov and Sergey Z. Vatsadze},
title = {Copper-Bispidine Complexes: Synthesis and Complex Stability Study},
journal = {ACS Omega},
year = {2016},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021%2Facsomega.6b00237},
number = {5},
pages = {854--867},
doi = {10.1021/acsomega.6b00237}
}
Cite this
MLA
Copy
Medved'ko, Aleksei V., et al. “Copper-Bispidine Complexes: Synthesis and Complex Stability Study.” ACS Omega, vol. 1, no. 5, Nov. 2016, pp. 854-867. https://doi.org/10.1021%2Facsomega.6b00237.