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, том 1 , издание 5 , страницы 854-867

Copper-Bispidine Complexes: Synthesis and Complex Stability Study

Тип публикации: Journal Article

Дата публикации: 2016-11-08

American Chemical Society (ACS)

ACS Omega

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SJR: 0.773

CiteScore: 7.1

Impact factor: 4.3

ISSN: 24701343

DOI: 10.1021/acsomega.6b00237

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PubMed ID: 31457168

General Chemistry

General Chemical Engineering

Краткое описание

A new series of dicarboxylic derivatives of bispidines have been synthesized to develop novel copper(II) complexes suitable as imaging agents for positron emission tomography. For characterization purposes, copper complexes of bispidines were synthesized in the pure form and in quantitative yields by neutralization of ligands with malachite. The formation of complexes and their stoichiometries were studied by potentiometric titration, cyclic voltammetry, and spectroscopic methods. The stability constants were found to be fairly suitable for copper cation fixation inside dianionic chelate molecules.

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Medved'ko A. V. et al. Copper-Bispidine Complexes: Synthesis and Complex Stability Study // ACS Omega. 2016. Vol. 1. No. 5. pp. 854-867.

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Medved'ko A. V., Egorova B. V., Komarova A. A., Rakhimov R. D., Krutko D. P., Kalmykov S. N., Vatsadze S. Z. Copper-Bispidine Complexes: Synthesis and Complex Stability Study // ACS Omega. 2016. Vol. 1. No. 5. pp. 854-867.

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TY - JOUR

DO - 10.1021/acsomega.6b00237

UR - https://doi.org/10.1021/acsomega.6b00237

TI - Copper-Bispidine Complexes: Synthesis and Complex Stability Study

T2 - ACS Omega

AU - Medved'ko, Aleksei V.

AU - Egorova, B. V.

AU - Komarova, Alina A

AU - Rakhimov, Rustem D

AU - Krutko, Dmitri P

AU - Kalmykov, Stepan N.

AU - Vatsadze, S Zh

PY - 2016

DA - 2016/11/08

PB - American Chemical Society (ACS)

SP - 854-867

IS - 5

VL - 1

PMID - 31457168

SN - 2470-1343

ER -

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@article{2016_Medved'ko,

author = {Aleksei V. Medved'ko and B. V. Egorova and Alina A Komarova and Rustem D Rakhimov and Dmitri P Krutko and Stepan N. Kalmykov and S Zh Vatsadze},

title = {Copper-Bispidine Complexes: Synthesis and Complex Stability Study},

journal = {ACS Omega},

year = {2016},

volume = {1},

publisher = {American Chemical Society (ACS)},

month = {nov},

url = {https://doi.org/10.1021/acsomega.6b00237},

number = {5},

pages = {854--867},

doi = {10.1021/acsomega.6b00237}

}

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Medved'ko, Aleksei V., et al. “Copper-Bispidine Complexes: Synthesis and Complex Stability Study.” ACS Omega, vol. 1, no. 5, Nov. 2016, pp. 854-867. https://doi.org/10.1021/acsomega.6b00237.