Open Access
Copper-Bispidine Complexes: Synthesis and Complex Stability Study
Aleksei V. Medved'ko
1
,
B. V. Egorova
1
,
Alina A Komarova
1
,
Rustem D Rakhimov
1
,
Dmitri P Krutko
1
,
Publication type: Journal Article
Publication date: 2016-11-08
scimago Q1
wos Q2
SJR: 0.773
CiteScore: 7.1
Impact factor: 4.3
ISSN: 24701343
PubMed ID:
31457168
General Chemistry
General Chemical Engineering
Abstract
A new series of dicarboxylic derivatives of bispidines have been synthesized to develop novel copper(II) complexes suitable as imaging agents for positron emission tomography. For characterization purposes, copper complexes of bispidines were synthesized in the pure form and in quantitative yields by neutralization of ligands with malachite. The formation of complexes and their stoichiometries were studied by potentiometric titration, cyclic voltammetry, and spectroscopic methods. The stability constants were found to be fairly suitable for copper cation fixation inside dianionic chelate molecules.
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30
Total citations:
30
Citations from 2024:
8
(26%)
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MLA
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GOST
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Medved'ko A. V. et al. Copper-Bispidine Complexes: Synthesis and Complex Stability Study // ACS Omega. 2016. Vol. 1. No. 5. pp. 854-867.
GOST all authors (up to 50)
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Medved'ko A. V., Egorova B. V., Komarova A. A., Rakhimov R. D., Krutko D. P., Kalmykov S. N., Vatsadze S. Z. Copper-Bispidine Complexes: Synthesis and Complex Stability Study // ACS Omega. 2016. Vol. 1. No. 5. pp. 854-867.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/acsomega.6b00237
UR - https://doi.org/10.1021/acsomega.6b00237
TI - Copper-Bispidine Complexes: Synthesis and Complex Stability Study
T2 - ACS Omega
AU - Medved'ko, Aleksei V.
AU - Egorova, B. V.
AU - Komarova, Alina A
AU - Rakhimov, Rustem D
AU - Krutko, Dmitri P
AU - Kalmykov, Stepan N.
AU - Vatsadze, Sergey Z.
PY - 2016
DA - 2016/11/08
PB - American Chemical Society (ACS)
SP - 854-867
IS - 5
VL - 1
PMID - 31457168
SN - 2470-1343
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2016_Medved'ko,
author = {Aleksei V. Medved'ko and B. V. Egorova and Alina A Komarova and Rustem D Rakhimov and Dmitri P Krutko and Stepan N. Kalmykov and Sergey Z. Vatsadze},
title = {Copper-Bispidine Complexes: Synthesis and Complex Stability Study},
journal = {ACS Omega},
year = {2016},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/acsomega.6b00237},
number = {5},
pages = {854--867},
doi = {10.1021/acsomega.6b00237}
}
Cite this
MLA
Copy
Medved'ko, Aleksei V., et al. “Copper-Bispidine Complexes: Synthesis and Complex Stability Study.” ACS Omega, vol. 1, no. 5, Nov. 2016, pp. 854-867. https://doi.org/10.1021/acsomega.6b00237.