Open Access
Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titaniumtert-Butoxy Halides, CpxTiXy(OtBu)4–(x+y)(x,y= 1, 2; X = Cl, Br)
Publication type: Journal Article
Publication date: 2018-07-20
scimago Q1
wos Q2
SJR: 0.773
CiteScore: 7.1
Impact factor: 4.3
ISSN: 24701343
PubMed ID:
31458952
General Chemistry
General Chemical Engineering
Abstract
Titanium tert-butoxy halides of the formula Cp x TiX y (O t Bu)4-(x+y) (x, y = 1, 2; X = Cl, Br) have been prepared thorough milling the reagents without solvent. In the case of the chloride derivatives, Cp2TiCl2 is used as a starting material; in the case of the bromides, a mixture of LiCp, TiBr4, and Li[O t Bu] is used. The stoichiometric ratios of the starting materials are reflected in the major products of the reactions. Single-crystal X-ray structures are reported for Cp2TiCl(O t Bu), Cp2TiBr(O t Bu), and CpTiBr2(O t Bu), as well as for Cp2TiCl(O i Pr) and a redetermination of Cp2TiCl(OMe). The tert-butoxy derivatives are notable for their nearly linear Ti-O-C angles (>170°) that reflect Ti-O π-bonding, an interpretation supported with density functional theory calculations.
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Boyde N. C., Steelman G. W., Hanusa T. P. Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titaniumtert-Butoxy Halides, CpxTiXy(OtBu)4–(x+y)(x,y= 1, 2; X = Cl, Br) // ACS Omega. 2018. Vol. 3. No. 7. pp. 8149-8159.
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Boyde N. C., Steelman G. W., Hanusa T. P. Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titaniumtert-Butoxy Halides, CpxTiXy(OtBu)4–(x+y)(x,y= 1, 2; X = Cl, Br) // ACS Omega. 2018. Vol. 3. No. 7. pp. 8149-8159.
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TY - JOUR
DO - 10.1021/acsomega.8b00943
UR - https://doi.org/10.1021/acsomega.8b00943
TI - Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titaniumtert-Butoxy Halides, CpxTiXy(OtBu)4–(x+y)(x,y= 1, 2; X = Cl, Br)
T2 - ACS Omega
AU - Boyde, Nicholas C
AU - Steelman, Grant W
AU - Hanusa, Timothy P.
PY - 2018
DA - 2018/07/20
PB - American Chemical Society (ACS)
SP - 8149-8159
IS - 7
VL - 3
PMID - 31458952
SN - 2470-1343
ER -
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BibTex (up to 50 authors)
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@article{2018_Boyde,
author = {Nicholas C Boyde and Grant W Steelman and Timothy P. Hanusa},
title = {Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titaniumtert-Butoxy Halides, CpxTiXy(OtBu)4–(x+y)(x,y= 1, 2; X = Cl, Br)},
journal = {ACS Omega},
year = {2018},
volume = {3},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acsomega.8b00943},
number = {7},
pages = {8149--8159},
doi = {10.1021/acsomega.8b00943}
}
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Boyde, Nicholas C., et al. “Multicomponent Mechanochemical Synthesis of Cyclopentadienyl Titaniumtert-Butoxy Halides, CpxTiXy(OtBu)4–(x+y)(x,y= 1, 2; X = Cl, Br).” ACS Omega, vol. 3, no. 7, Jul. 2018, pp. 8149-8159. https://doi.org/10.1021/acsomega.8b00943.