Open Access
Open access
volume 2 issue 2 pages 148-152

Electrochemical Hydrosilylation of Alkynes

Tony Biremond 1
Philippe Jubault 1
1
 
Normandie Univ, INSA Rouen, UNIROUEN, CNRS, COBRA (UMR 6014), 76000 Rouen, France
Publication typeJournal Article
Publication date2022-02-10
scimago Q1
wos Q2
SJR0.982
CiteScore6.0
Impact factor4.4
ISSN2694247X
Abstract
Herein, the electrochemical hydrosilylation of alkynes is reported. In the presence of the Suginome reagent (PhMe2Si–Bpin), a large panel of terminal alkynes and internal alkynes was successfully converted into the hydrosilylated product in good to excellent yields and good selectivity in favor of the linear product. Preliminary mechanistic study supported the involvement of a silyl radical, which reacted on the alkyne.
Found 
Found 

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GOST |
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GOST Copy
Biremond T. et al. Electrochemical Hydrosilylation of Alkynes // ACS Organic & Inorganic Au. 2022. Vol. 2. No. 2. pp. 148-152.
GOST all authors (up to 50) Copy
Biremond T., Jubault P., Poisson T. Electrochemical Hydrosilylation of Alkynes // ACS Organic & Inorganic Au. 2022. Vol. 2. No. 2. pp. 148-152.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/acsorginorgau.1c00035
UR - https://doi.org/10.1021/acsorginorgau.1c00035
TI - Electrochemical Hydrosilylation of Alkynes
T2 - ACS Organic & Inorganic Au
AU - Biremond, Tony
AU - Jubault, Philippe
AU - Poisson, Thomas
PY - 2022
DA - 2022/02/10
PB - American Chemical Society (ACS)
SP - 148-152
IS - 2
VL - 2
PMID - 36855456
SN - 2694-247X
ER -
BibTex |
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BibTex (up to 50 authors) Copy
@article{2022_Biremond,
author = {Tony Biremond and Philippe Jubault and Thomas Poisson},
title = {Electrochemical Hydrosilylation of Alkynes},
journal = {ACS Organic & Inorganic Au},
year = {2022},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acsorginorgau.1c00035},
number = {2},
pages = {148--152},
doi = {10.1021/acsorginorgau.1c00035}
}
MLA
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MLA Copy
Biremond, Tony, et al. “Electrochemical Hydrosilylation of Alkynes.” ACS Organic & Inorganic Au, vol. 2, no. 2, Feb. 2022, pp. 148-152. https://doi.org/10.1021/acsorginorgau.1c00035.