N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes
Publication type: Journal Article
Publication date: 2017-02-20
scimago Q1
wos Q1
SJR: 1.623
CiteScore: 12.5
Impact factor: 7.3
ISSN: 21680485
General Chemistry
General Chemical Engineering
Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Abstract
Bimetallic Pd–Au catalyst was prepared by depositing the Pd–Au alloy nanoparticles on polyaniline-functionalized carbon nanotubes (PANI-CNT) and the resulting Pd–Au/PANI-CNT catalyst exhibited excellent catalytic activity for the N-formylation of pyrrolidine using CO2/H2. The structural and electronic properties of the Pd–Au/PANI-CNT was characterized by X-ray powder diffraction (XRD), nitrogen adsorption–desorption, transmission electron microscopy (TEM), high angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), and X-ray photoelectron spectroscopy (XPS). Under optimized conditions, an N-formylpyrrolidine yield of 98.3% was obtained from pyrrolidine and CO2/H2 at 125 °C by using Pd–Au/PANI-CNT with a Pd/Au molar ratio of 1:1. Our research further reveals that Pd atoms should be the true active sites for the hydrogenation reaction and the N-formylation reaction might occur mainly over Pd atoms or over the interface between Pd atoms and Au atoms for the bimetallic Pd–Au/PANI-CNT...
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91
Total citations:
91
Citations from 2024:
17
(18%)
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GOST
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Ju P. et al. N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes // ACS Sustainable Chemistry and Engineering. 2017. Vol. 5. No. 3. pp. 2516-2528.
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Ju P., Chen J., Chen A., Chen L., Yu Y. N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes // ACS Sustainable Chemistry and Engineering. 2017. Vol. 5. No. 3. pp. 2516-2528.
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TY - JOUR
DO - 10.1021/acssuschemeng.6b02865
UR - https://doi.org/10.1021/acssuschemeng.6b02865
TI - N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes
T2 - ACS Sustainable Chemistry and Engineering
AU - Ju, Pengpeng
AU - Chen, Jin-Zhu
AU - Chen, Aibing
AU - Chen, Limin
AU - Yu, Yifeng
PY - 2017
DA - 2017/02/20
PB - American Chemical Society (ACS)
SP - 2516-2528
IS - 3
VL - 5
SN - 2168-0485
ER -
Cite this
BibTex (up to 50 authors)
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@article{2017_Ju,
author = {Pengpeng Ju and Jin-Zhu Chen and Aibing Chen and Limin Chen and Yifeng Yu},
title = {N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes},
journal = {ACS Sustainable Chemistry and Engineering},
year = {2017},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/acssuschemeng.6b02865},
number = {3},
pages = {2516--2528},
doi = {10.1021/acssuschemeng.6b02865}
}
Cite this
MLA
Copy
Ju, Pengpeng, et al. “N-Formylation of Amines with CO2 and H2 Using Pd–Au Bimetallic Catalysts Supported on Polyaniline-Functionalized Carbon Nanotubes.” ACS Sustainable Chemistry and Engineering, vol. 5, no. 3, Feb. 2017, pp. 2516-2528. https://doi.org/10.1021/acssuschemeng.6b02865.
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