Selective Recovery of Li and Fe from Spent Lithium-Ion Batteries by an Environmentally Friendly Mechanochemical Approach
Тип публикации: Journal Article
Дата публикации: 2018-07-17
scimago Q1
wos Q1
БС1
SJR: 1.623
CiteScore: 12.5
Impact factor: 7.3
ISSN: 21680485
General Chemistry
General Chemical Engineering
Environmental Chemistry
Renewable Energy, Sustainability and the Environment
Краткое описание
Recycling of spent LiFePO4 batteries has drawn recent attention relating to recovering their high contents of rare elements and negating potential negative environmental effects of their disposal. However, the stable crystal structure of LiFePO4 materials has prevented the development of a recycling process with high selectivity and extraction efficiency. We report the selective extraction of Fe and Li from spent LiFePO4 batteries via an environmentally friendly mechanochemical process with oxalic acid. With the use of a mechanochemical treatment and water leaching, the Li extraction efficiency can be improved to 99%. Furthermore, 94% of Fe can be simultaneously recovered as FeC2O4·2H2O. To understand the reaction mechanism and determine the optimum reaction conditions, we investigated various parameters, including the LiFePO4 to oxalic acid mass ratio, rotation speed, milling time, and ball-to-powder mass ratio. Moreover, metal ions from the water leaching process were recovered by chemical precipitation...
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ГОСТ
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Fan E. et al. Selective Recovery of Li and Fe from Spent Lithium-Ion Batteries by an Environmentally Friendly Mechanochemical Approach // ACS Sustainable Chemistry and Engineering. 2018. Vol. 6. No. 8. pp. 11029-11035.
ГОСТ со всеми авторами (до 50)
Скопировать
Fan E., Li L., Zhang X., Bian Y., Xue Q., Wu J., Wu F., Chen R. Selective Recovery of Li and Fe from Spent Lithium-Ion Batteries by an Environmentally Friendly Mechanochemical Approach // ACS Sustainable Chemistry and Engineering. 2018. Vol. 6. No. 8. pp. 11029-11035.
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TY - JOUR
DO - 10.1021/acssuschemeng.8b02503
UR - https://doi.org/10.1021/acssuschemeng.8b02503
TI - Selective Recovery of Li and Fe from Spent Lithium-Ion Batteries by an Environmentally Friendly Mechanochemical Approach
T2 - ACS Sustainable Chemistry and Engineering
AU - Fan, Ersha
AU - Li, Li
AU - Zhang, Xiaoxiao
AU - Bian, Yifan
AU - Xue, Qing
AU - Wu, Jiawei
AU - Wu, Feng
AU - Chen, Renjie
PY - 2018
DA - 2018/07/17
PB - American Chemical Society (ACS)
SP - 11029-11035
IS - 8
VL - 6
SN - 2168-0485
ER -
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BibTex (до 50 авторов)
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@article{2018_Fan,
author = {Ersha Fan and Li Li and Xiaoxiao Zhang and Yifan Bian and Qing Xue and Jiawei Wu and Feng Wu and Renjie Chen},
title = {Selective Recovery of Li and Fe from Spent Lithium-Ion Batteries by an Environmentally Friendly Mechanochemical Approach},
journal = {ACS Sustainable Chemistry and Engineering},
year = {2018},
volume = {6},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/acssuschemeng.8b02503},
number = {8},
pages = {11029--11035},
doi = {10.1021/acssuschemeng.8b02503}
}
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MLA
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Fan, Ersha, et al. “Selective Recovery of Li and Fe from Spent Lithium-Ion Batteries by an Environmentally Friendly Mechanochemical Approach.” ACS Sustainable Chemistry and Engineering, vol. 6, no. 8, Jul. 2018, pp. 11029-11035. https://doi.org/10.1021/acssuschemeng.8b02503.