Layer-by-layer polyelectrolyte/inhibitor nanostructures for metal corrosion protection
Publication type: Journal Article
Publication date: 2010-06-15
scimago Q1
wos Q1
SJR: 1.921
CiteScore: 14.5
Impact factor: 8.2
ISSN: 19448244, 19448252
General Materials Science
Abstract
Multicomponent coating formed by polyelectrolyte multilayers opens new opportunities for anticorrosion protection. Here we demonstrate a novel method of corrosion protection based on formation and deposition of polyelectrolyte multilayers on aluminum and steel alloys, analysis of different polyelectrolyte compositions (strong−strong, strong−weak, weak−weak) as candidates for corrosion protective layers. The multilayer nanonetwork exhibits very high corrosion protection because of the nature and versatility of the polyelectrolyte complex. The anticorrosion activity of the coating is based on the following mechanisms: (1) pH buffer formed by polybase and polyacid complex suppress pH changes caused by corrosion degradation; (2) coating regeneration and defect elimination due to relative mobility of polymer chains in swollen state; (3) polyelectrolyte layers form a carrier for inhibitor allowing its release on demand; (4) polyelectrolyte nanonetwork provides a barrier between surface and environment. We optim...
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182
Total citations:
182
Citations from 2024:
19
(10%)
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GOST
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Andreeva D., Skorb E. V., Shchukin D. Layer-by-layer polyelectrolyte/inhibitor nanostructures for metal corrosion protection // ACS applied materials & interfaces. 2010. Vol. 2. No. 7. pp. 1954-1962.
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Andreeva D., Skorb E. V., Shchukin D. Layer-by-layer polyelectrolyte/inhibitor nanostructures for metal corrosion protection // ACS applied materials & interfaces. 2010. Vol. 2. No. 7. pp. 1954-1962.
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TY - JOUR
DO - 10.1021/am1002712
UR - https://doi.org/10.1021/am1002712
TI - Layer-by-layer polyelectrolyte/inhibitor nanostructures for metal corrosion protection
T2 - ACS applied materials & interfaces
AU - Andreeva, D.V.
AU - Skorb, Ekaterina V.
AU - Shchukin, Dmitry
PY - 2010
DA - 2010/06/15
PB - American Chemical Society (ACS)
SP - 1954-1962
IS - 7
VL - 2
SN - 1944-8244
SN - 1944-8252
ER -
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BibTex (up to 50 authors)
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@article{2010_Andreeva,
author = {D.V. Andreeva and Ekaterina V. Skorb and Dmitry Shchukin},
title = {Layer-by-layer polyelectrolyte/inhibitor nanostructures for metal corrosion protection},
journal = {ACS applied materials & interfaces},
year = {2010},
volume = {2},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/am1002712},
number = {7},
pages = {1954--1962},
doi = {10.1021/am1002712}
}
Cite this
MLA
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Andreeva, D.V., et al. “Layer-by-layer polyelectrolyte/inhibitor nanostructures for metal corrosion protection.” ACS applied materials & interfaces, vol. 2, no. 7, Jun. 2010, pp. 1954-1962. https://doi.org/10.1021/am1002712.
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