ACS applied materials & interfaces, volume 5, issue 23, pages 12387-12393
Oxidation Reaction of Polyether-Based Material and Its Suppression in Lithium Rechargeable Battery Using 4 V Class Cathode, LiNi1/3Mn1/3Co1/3O2
Takeshi Kobayashi
1
,
Yo Kobayashi
1
,
Masato Tabuchi
2
,
Kumi Shono
1
,
Yasutaka Ohno
3
,
Yuichi Mita
1
,
Hajime Miyashiro
1
2
DAISO CO., 9 Ohtakasu-cyo, Amagasaki, Hyogo 660-0842, Japan
|
3
Electric Power Engineering Systems Co., 2-11-1 Iwado-kita, Komae, Tokyo 201-8511, Japan
|
Publication type: Journal Article
Publication date: 2013-11-18
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
The all solid-state lithium battery with polyether-based solid polymer electrolyte (SPE) is regarded as one of next-generation lithium batteries, and has potential for sufficient safety because of the flammable-electrolyte-free system. It has been believed that polyether-based SPE is oxidized at the polymer/electrode interface with 4 V class cathodes. Therefore, it has been used for electric devices such as organic transistor, and lithium battery under 3 V. We estimated decomposition reaction of polyether used as SPE of all solid-state lithium battery. We first identified the decomposed parts of polyether-based SPE and the conservation of most main chain framework, considering the results of SPE analysis after long cycle operations. The oxidation reaction was found to occur slightly at the ether bond in the main chain with the branched side chain. Moreover, we resolved the issue by introducing a self-sacrificing buffer layer at the interface. The introduction of sodium carboxymethyl cellulose (CMC) to the 4 V class cathode surface led to the suppression of SPE decomposition at the interface as a result of the preformation of a buffer layer from CMC, which was confirmed by the irreversible exothermic reaction during the first charge, using electrochemical calorimetry. The attained 1500 cycle operation is 1 order of magnitude longer than those of previously reported polymer systems, and compatible with those of reported commercial liquid systems. The above results indicate to proceed to an intensive research toward the realization of 4 V class "safe" lithium polymer batteries without flammable liquid electrolyte.
Top-30
Citations by journals
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1
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3
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Journal of Power Sources
3 publications, 9.38%
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ACS applied materials & interfaces
3 publications, 9.38%
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Small
2 publications, 6.25%
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2 publications, 6.25%
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2 publications, 6.25%
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1 publication, 3.13%
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InfoMat
1 publication, 3.13%
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Electrochemical Energy Reviews
1 publication, 3.13%
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Batteries
1 publication, 3.13%
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Electrochimica Acta
1 publication, 3.13%
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Nano Energy
1 publication, 3.13%
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1 publication, 3.13%
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Fluid Phase Equilibria
1 publication, 3.13%
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Solid State Ionics
1 publication, 3.13%
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Carbon Energy
1 publication, 3.13%
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Chemistry - A European Journal
1 publication, 3.13%
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Angewandte Chemie
1 publication, 3.13%
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Angewandte Chemie - International Edition
1 publication, 3.13%
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RSC Advances
1 publication, 3.13%
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ACS Materials Au
1 publication, 3.13%
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International Journal of Applied Ceramic Technology
1 publication, 3.13%
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Russian Chemical Reviews
1 publication, 3.13%
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1
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3
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Citations by publishers
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2
4
6
8
10
12
14
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Wiley
13 publications, 40.63%
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Elsevier
8 publications, 25%
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American Chemical Society (ACS)
7 publications, 21.88%
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Springer Nature
1 publication, 3.13%
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Multidisciplinary Digital Publishing Institute (MDPI)
1 publication, 3.13%
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Royal Society of Chemistry (RSC)
1 publication, 3.13%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 3.13%
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2
4
6
8
10
12
14
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Kobayashi T. et al. Oxidation Reaction of Polyether-Based Material and Its Suppression in Lithium Rechargeable Battery Using 4 V Class Cathode, LiNi1/3Mn1/3Co1/3O2 // ACS applied materials & interfaces. 2013. Vol. 5. No. 23. pp. 12387-12393.
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Kobayashi T., Kobayashi Y., Tabuchi M., Shono K., Ohno Y., Mita Y., Miyashiro H. Oxidation Reaction of Polyether-Based Material and Its Suppression in Lithium Rechargeable Battery Using 4 V Class Cathode, LiNi1/3Mn1/3Co1/3O2 // ACS applied materials & interfaces. 2013. Vol. 5. No. 23. pp. 12387-12393.
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RIS
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TY - JOUR
DO - 10.1021/am403304j
UR - https://doi.org/10.1021/am403304j
TI - Oxidation Reaction of Polyether-Based Material and Its Suppression in Lithium Rechargeable Battery Using 4 V Class Cathode, LiNi1/3Mn1/3Co1/3O2
T2 - ACS applied materials & interfaces
AU - Tabuchi, Masato
AU - Shono, Kumi
AU - Ohno, Yasutaka
AU - Mita, Yuichi
AU - Miyashiro, Hajime
AU - Kobayashi, Takeshi
AU - Kobayashi, Yo
PY - 2013
DA - 2013/11/18 00:00:00
PB - American Chemical Society (ACS)
SP - 12387-12393
IS - 23
VL - 5
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2013_Kobayashi,
author = {Masato Tabuchi and Kumi Shono and Yasutaka Ohno and Yuichi Mita and Hajime Miyashiro and Takeshi Kobayashi and Yo Kobayashi},
title = {Oxidation Reaction of Polyether-Based Material and Its Suppression in Lithium Rechargeable Battery Using 4 V Class Cathode, LiNi1/3Mn1/3Co1/3O2},
journal = {ACS applied materials & interfaces},
year = {2013},
volume = {5},
publisher = {American Chemical Society (ACS)},
month = {nov},
url = {https://doi.org/10.1021/am403304j},
number = {23},
pages = {12387--12393},
doi = {10.1021/am403304j}
}
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MLA
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Kobayashi, Takeshi, et al. “Oxidation Reaction of Polyether-Based Material and Its Suppression in Lithium Rechargeable Battery Using 4 V Class Cathode, LiNi1/3Mn1/3Co1/3O2.” ACS applied materials & interfaces, vol. 5, no. 23, Nov. 2013, pp. 12387-12393. https://doi.org/10.1021/am403304j.