ACS applied materials & interfaces, volume 1, issue 8, pages 1650-1655
Compatibilization by Homopolymer: Significant Improvements in the Modulus and Tensile Strength of PPC/PMMA Blends by the Addition of a Small Amount of PVAc
Publication type: Journal Article
Publication date: 2009-08-05
Journal:
ACS applied materials & interfaces
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 9.5
ISSN: 19448244, 19448252
General Materials Science
Abstract
Poly(propylene carbonate) (PPC), a polymer produced from CO2, has been melt-mixed with 30 wt % poly(methyl methacrylate) (PMMA) with the aim of enhancing the physical properties of PPC for practical use but keeping a relatively high CO2 fixing rate in the compound. The observation of a coarse phase structure with a large PMMA domain size and a large size distribution in the blend indicates the immiscibility between PPC and PMMA. The addition of a small amount of poly(vinyl acetate) (PVAc) not only shifts the glass transition temperatures (T(g)'s) of both PPC and PMMA markedly but also significantly increases the modulus and tensile strength of the blend. The prepared compound with 5 per hundred parts of resin PVAc shows a 26 times higher elastic modulus and an approximately 3.8 times higher tensile strength than pure PPC at room temperature. The morphological investigation indicates that the incorporation to PVAC not only induces the finer dispersion of PMMA in the PPC matrix but also results in the phase transformation from a sea-island to a co-continuous structure.
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1 publication, 1.37%
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1 publication, 1.37%
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Citations by publishers
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20
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Elsevier
20 publications, 27.4%
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Springer Nature
15 publications, 20.55%
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American Chemical Society (ACS)
11 publications, 15.07%
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Wiley
9 publications, 12.33%
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6 publications, 8.22%
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Taylor & Francis
4 publications, 5.48%
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Multidisciplinary Digital Publishing Institute (MDPI)
3 publications, 4.11%
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American Institute of Physics (AIP)
1 publication, 1.37%
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Polymer Society of Korea
1 publication, 1.37%
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IOP Publishing
1 publication, 1.37%
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Trans Tech Publications
1 publication, 1.37%
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Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 1.37%
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20
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Li Y., Shimizu H. Compatibilization by Homopolymer: Significant Improvements in the Modulus and Tensile Strength of PPC/PMMA Blends by the Addition of a Small Amount of PVAc // ACS applied materials & interfaces. 2009. Vol. 1. No. 8. pp. 1650-1655.
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Li Y., Shimizu H. Compatibilization by Homopolymer: Significant Improvements in the Modulus and Tensile Strength of PPC/PMMA Blends by the Addition of a Small Amount of PVAc // ACS applied materials & interfaces. 2009. Vol. 1. No. 8. pp. 1650-1655.
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TY - JOUR
DO - 10.1021/am900314k
UR - https://doi.org/10.1021/am900314k
TI - Compatibilization by Homopolymer: Significant Improvements in the Modulus and Tensile Strength of PPC/PMMA Blends by the Addition of a Small Amount of PVAc
T2 - ACS applied materials & interfaces
AU - Li, Yongjin
AU - Shimizu, Hiroshi
PY - 2009
DA - 2009/08/05 00:00:00
PB - American Chemical Society (ACS)
SP - 1650-1655
IS - 8
VL - 1
SN - 1944-8244
SN - 1944-8252
ER -
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@article{2009_Li,
author = {Yongjin Li and Hiroshi Shimizu},
title = {Compatibilization by Homopolymer: Significant Improvements in the Modulus and Tensile Strength of PPC/PMMA Blends by the Addition of a Small Amount of PVAc},
journal = {ACS applied materials & interfaces},
year = {2009},
volume = {1},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/am900314k},
number = {8},
pages = {1650--1655},
doi = {10.1021/am900314k}
}
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MLA
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Li, Yongjin, and Hiroshi Shimizu. “Compatibilization by Homopolymer: Significant Improvements in the Modulus and Tensile Strength of PPC/PMMA Blends by the Addition of a Small Amount of PVAc.” ACS applied materials & interfaces, vol. 1, no. 8, Aug. 2009, pp. 1650-1655. https://doi.org/10.1021/am900314k.