Crystal Growth and Design

, volume 10 , issue 7 , pages 2969-2976

Insight into the growth of multiple branched MnOOH nanorods

Yu Li ^{1, 2}

Haiyan Tan ³

Oleg Lebedev ³

J. Verbeeck ³

Ellen Biermans ³

G. Van Tendeloo ³

Bao-Lian Su ^{1, 2}

Hide authors affiliations Show authors affiliations: 3 affiliations

State key Laboratory of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, 122 Luoshi Road, 430070, Wuhan, Hubei, China |

Laboratory of Inorganic Materials Chemistry (CMI), The University of Namur (FUNDP), 61 rue de Bruxelles, B-5000 Namur, Belgium |

EMAT, University of Antwerp, 171 Groenenborgerlaan, B-2020 Antwerpen, Belgium |

Publication type: Journal Article

Publication date: 2010-06-08

American Chemical Society (ACS)

Crystal Growth and Design

scimago Q2

wos Q1

SJR: 0.633

CiteScore: 5.6

Impact factor: 3.4

ISSN: 15287483, 15287505

DOI: 10.1021/cg100009k

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General Chemistry

Condensed Matter Physics

General Materials Science

Abstract

Multiple branched manganese oxide hydroxide (MnOOH) nanorods prepared by a hydrothermal process were extensively studied by transmission electron microscopy (TEM). A model of the branch formation is proposed together with a study of the interface structure. The sword-like tip plays a crucial role for the nanorods to form different shapes. Importantly, the branching occurs at an angle of around either 57° or 123°. Specifically, a (111) twin plane can only be formed at the interface with a 123° angle. The interfaces formed with a 57° angle usually contain edge dislocations. Electron energy loss spectroscopy (EELS) demonstrates that the whole crystal has a uniform chemical composition. Interestingly, an epitaxial growth of Mn3O4 at the radial surface was also observed under electron beam irradiation; this is because of the rough purification of the products. The proposed mechanism is expected to shed light on the branched/dendrite nanostructure growth and to provide opportunities for further novel nanomateri...

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Cite this

GOST |

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GOST Copy

Li Yu. et al. Insight into the growth of multiple branched MnOOH nanorods // Crystal Growth and Design. 2010. Vol. 10. No. 7. pp. 2969-2976.

GOST all authors (up to 50) Copy

Li Yu., Tan H., Lebedev O., Verbeeck J., Biermans E., Van Tendeloo G., Su B. Insight into the growth of multiple branched MnOOH nanorods // Crystal Growth and Design. 2010. Vol. 10. No. 7. pp. 2969-2976.

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/cg100009k

UR - https://doi.org/10.1021/cg100009k

TI - Insight into the growth of multiple branched MnOOH nanorods

T2 - Crystal Growth and Design

AU - Li, Yu

AU - Tan, Haiyan

AU - Lebedev, Oleg

AU - Verbeeck, J.

AU - Biermans, Ellen

AU - Van Tendeloo, G.

AU - Su, Bao-Lian

PY - 2010

DA - 2010/06/08

PB - American Chemical Society (ACS)

SP - 2969-2976

IS - 7

VL - 10

SN - 1528-7483

SN - 1528-7505

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2010_Li,

author = {Yu Li and Haiyan Tan and Oleg Lebedev and J. Verbeeck and Ellen Biermans and G. Van Tendeloo and Bao-Lian Su},

title = {Insight into the growth of multiple branched MnOOH nanorods},

journal = {Crystal Growth and Design},

year = {2010},

volume = {10},

publisher = {American Chemical Society (ACS)},

month = {jun},

url = {https://doi.org/10.1021/cg100009k},

number = {7},

pages = {2969--2976},

doi = {10.1021/cg100009k}

}

MLA

Cite this

MLA Copy

Li, Yu., et al. “Insight into the growth of multiple branched MnOOH nanorods.” Crystal Growth and Design, vol. 10, no. 7, Jun. 2010, pp. 2969-2976. https://doi.org/10.1021/cg100009k.

Publisher

American Chemical Society (ACS)

Journal

Crystal Growth and Design

scimago Q2

wos Q1

SJR

0.633

CiteScore

5.6

Impact factor

3.4

ISSN

15287483 (Print)

15287505 (Electronic)