Crystallization of 4′-Hydroxyacetophenone from Water: Control of Polymorphism via Phase Diagram Studies
Carlos Bernardes
1, 2
,
Publication type: Journal Article
Publication date: 2012-05-25
scimago Q2
wos Q1
SJR: 0.633
CiteScore: 5.6
Impact factor: 3.4
ISSN: 15287483, 15287505
General Chemistry
Condensed Matter Physics
General Materials Science
Abstract
The preparation of polymorphs and solvates and the characterization of their stability domains have received considerable attention in recent years, due to the importance of these studies for fundamental research and for the production of new materials for task-specific applications. In this work, the selective and reproducible crystallization of different solid forms of 4′-hydroxyacetophenone (HAP) from water was investigated, through the determination of a temperature–concentration (T–cHAP) phase diagram. This determination was mainly based on gravimetric solubility measurements, slurry tests, and metastable zone width (MZW) studies with thermometric and turbidity detection. The experimental conditions for the formation of five different HAP phases by cooling crystallization could be established: the previously characterized anhydrous forms I and II and the hydrate HAP·1.5H2O (H1), and two new hydrates, one of stoichiometry HAP·3H2O (H2) and another (H3) which proved too unstable for a stoichiometry det...
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GOST
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Bernardes C., Piedade M. F. M. Crystallization of 4′-Hydroxyacetophenone from Water: Control of Polymorphism via Phase Diagram Studies // Crystal Growth and Design. 2012. Vol. 12. No. 6. pp. 2932-2941.
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Bernardes C., Piedade M. F. M. Crystallization of 4′-Hydroxyacetophenone from Water: Control of Polymorphism via Phase Diagram Studies // Crystal Growth and Design. 2012. Vol. 12. No. 6. pp. 2932-2941.
Cite this
RIS
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TY - JOUR
DO - 10.1021/cg300134z
UR - https://doi.org/10.1021/cg300134z
TI - Crystallization of 4′-Hydroxyacetophenone from Water: Control of Polymorphism via Phase Diagram Studies
T2 - Crystal Growth and Design
AU - Bernardes, Carlos
AU - Piedade, M. F. M.
PY - 2012
DA - 2012/05/25
PB - American Chemical Society (ACS)
SP - 2932-2941
IS - 6
VL - 12
SN - 1528-7483
SN - 1528-7505
ER -
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BibTex (up to 50 authors)
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@article{2012_Bernardes,
author = {Carlos Bernardes and M. F. M. Piedade},
title = {Crystallization of 4′-Hydroxyacetophenone from Water: Control of Polymorphism via Phase Diagram Studies},
journal = {Crystal Growth and Design},
year = {2012},
volume = {12},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/cg300134z},
number = {6},
pages = {2932--2941},
doi = {10.1021/cg300134z}
}
Cite this
MLA
Copy
Bernardes, Carlos, et al. “Crystallization of 4′-Hydroxyacetophenone from Water: Control of Polymorphism via Phase Diagram Studies.” Crystal Growth and Design, vol. 12, no. 6, May. 2012, pp. 2932-2941. https://doi.org/10.1021/cg300134z.