Crystal Structure of the Novel Complex Cobalt Oxide Sr0.7 Y 0.3 CoO2.62
S.Ya. Istomin
1
,
J. Grins
1
,
Gunnar Svensson
1
,
G. Svensson
1
,
O A Drozhzhin
1
,
V. L. Kozhevnikov
1
,
E. V. ANTIPOV
1
,
J. Paul Attfield
1
,
J. P. Attfield
1
Publication type: Journal Article
Publication date: 2003-09-11
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The perovskite-related crystal structure of the compound Sr0.7Y0.3CoO2.62 was determined and refined using synchrotron X-ray and neutron powder diffraction, in space group I4/mmm, a = 7.6237(8) A and c = 15.314(2) A, to RI = 0.041 in the synchrotron data set. It contains layers of CoO6 octahedra, perpendicular to the c axis, alternating with partially disordered oxygen-deficient layers. Further characterization of the structure using electron diffraction and high-resolution electron microscopy showed that an additional superstructure was present in some of the crystallites. The structure represents a new type of layered ordering of oxygen vacancies in oxygen-deficient perovskites. Possible local atom arrangements in the oxygen-deficient layers and the structural relationship to the resembling brownmillerite-type structure for ABO2.5 compounds are discussed.
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Istomin S. Y. et al. Crystal Structure of the Novel Complex Cobalt Oxide Sr0.7Y 0.3CoO2.62 // Chemistry of Materials. 2003. Vol. 15. No. 21. pp. 4012-4020.
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Istomin S. Y., Istomin S., Grins J., Svensson G., Svensson G., Drozhzhin O. A., Drozhzhin O. A., Kozhevnikov V. L., Antipov E. V., ANTIPOV E. V., Attfield J. P., Attfield J. P. Crystal Structure of the Novel Complex Cobalt Oxide Sr0.7Y 0.3CoO2.62 // Chemistry of Materials. 2003. Vol. 15. No. 21. pp. 4012-4020.
Cite this
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TY - JOUR
DO - 10.1021/cm034263e
UR - https://pubs.acs.org/doi/10.1021/cm034263e
TI - Crystal Structure of the Novel Complex Cobalt Oxide Sr0.7Y 0.3CoO2.62
T2 - Chemistry of Materials
AU - Istomin, Sergey Ya.
AU - Istomin, S.Ya.
AU - Grins, J.
AU - Svensson, Gunnar
AU - Svensson, G.
AU - Drozhzhin, Oleg A.
AU - Drozhzhin, O A
AU - Kozhevnikov, V. L.
AU - Antipov, Evgeny V.
AU - ANTIPOV, E. V.
AU - Attfield, J. Paul
AU - Attfield, J. P.
PY - 2003
DA - 2003/09/11
PB - American Chemical Society (ACS)
SP - 4012-4020
IS - 21
VL - 15
SN - 0897-4756
SN - 1520-5002
ER -
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BibTex (up to 50 authors)
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@article{2003_Istomin,
author = {Sergey Ya. Istomin and S.Ya. Istomin and J. Grins and Gunnar Svensson and G. Svensson and Oleg A. Drozhzhin and O A Drozhzhin and V. L. Kozhevnikov and Evgeny V. Antipov and E. V. ANTIPOV and J. Paul Attfield and J. P. Attfield},
title = {Crystal Structure of the Novel Complex Cobalt Oxide Sr0.7Y 0.3CoO2.62},
journal = {Chemistry of Materials},
year = {2003},
volume = {15},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://pubs.acs.org/doi/10.1021/cm034263e},
number = {21},
pages = {4012--4020},
doi = {10.1021/cm034263e}
}
Cite this
MLA
Copy
Istomin, Sergey Ya., et al. “Crystal Structure of the Novel Complex Cobalt Oxide Sr0.7Y 0.3CoO2.62.” Chemistry of Materials, vol. 15, no. 21, Sep. 2003, pp. 4012-4020. https://pubs.acs.org/doi/10.1021/cm034263e.