Chemistry of Materials, volume 16, issue 6, pages 1048-1055

Crystal Structure, Polymorphism, and Properties of the New Vanadyl Phosphate Na4VO(PO4)2

Panin Rodion V
Shpanchenko Roman V.
Mironov Andrei V.
Velikodny Yuri A.
Tarnopolsky Vasily A.
Kaul Enrique E. 2
2
 
Max Planck Institute for Chemical Physics of Solids, Max Planck Society
3
 
Christoph Geibel, Physics of Quantum Materials, Max Planck Institute for Chemical Physics of Solids, Max Planck Society
Publication typeJournal Article
Publication date2004-02-10
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor8.6
ISSN08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The new vanadyl phosphate Na4VO(PO4)2 was synthesized and investigated by X-ray powder and single-crystal diffraction, high-temperature X-ray diffraction, electron diffraction, high-resolution electron microscopy, thermal analysis, magnetic susceptibility, and conductivity measurements. The compound undergoes a reversible phase transition at about 200 °C. The crystal structure of low-temperature β-Na4VO(PO4)2 was solved using X-ray single-crystal data. This phase has an orthorhombic unit cell with lattice parameters a = 16.0068(12) A, b = 14.5129(8) A, c = 7.0231(5) A, S.G. Pbca, and Z = 8. The crystal structure of β-Na4VO(PO4)2 is built by isolated chains formed by corner-shared V4+O6 octahedra linked additionally via corners by two PO4 tetrahedra. All chains in the structure are equivalent. Na cations are located between the chains in an ordered manner. High-temperature α-Na4VO(PO4)2 also has an orthorhombic cell with lattice parameters a = 15.595(1) A, b = 14.651(2) A, c = 7.0262(6) A, S.G. Ibam, and Z...

Citations by journals

1
2
Journal of Solid State Chemistry
Journal of Solid State Chemistry, 2, 10%
Journal of Solid State Chemistry
2 publications, 10%
Chemistry of Materials
Chemistry of Materials, 2, 10%
Chemistry of Materials
2 publications, 10%
Russian Chemical Bulletin
Russian Chemical Bulletin, 1, 5%
Russian Chemical Bulletin
1 publication, 5%
Physical Review B
Physical Review B, 1, 5%
Physical Review B
1 publication, 5%
Materials Today Physics
Materials Today Physics, 1, 5%
Materials Today Physics
1 publication, 5%
Journal of Colloid and Interface Science
Journal of Colloid and Interface Science, 1, 5%
Journal of Colloid and Interface Science
1 publication, 5%
Solid State Sciences
Solid State Sciences, 1, 5%
Solid State Sciences
1 publication, 5%
Electrochimica Acta
Electrochimica Acta, 1, 5%
Electrochimica Acta
1 publication, 5%
Electrochemistry Communications
Electrochemistry Communications, 1, 5%
Electrochemistry Communications
1 publication, 5%
ChemInform
ChemInform, 1, 5%
ChemInform
1 publication, 5%
Zeitschrift fur Anorganische und Allgemeine Chemie
Zeitschrift fur Anorganische und Allgemeine Chemie, 1, 5%
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 5%
Inorganic Chemistry
Inorganic Chemistry, 1, 5%
Inorganic Chemistry
1 publication, 5%
ACS applied materials & interfaces
ACS applied materials & interfaces, 1, 5%
ACS applied materials & interfaces
1 publication, 5%
Annual Reports Section A (Inorganic Chemistry)
Annual Reports Section A (Inorganic Chemistry), 1, 5%
Annual Reports Section A (Inorganic Chemistry)
1 publication, 5%
Physical Chemistry Chemical Physics
Physical Chemistry Chemical Physics, 1, 5%
Physical Chemistry Chemical Physics
1 publication, 5%
CrystEngComm
CrystEngComm, 1, 5%
CrystEngComm
1 publication, 5%
Canadian Mineralogist, 1, 5%
Canadian Mineralogist
1 publication, 5%
Journal of Materials Chemistry A
Journal of Materials Chemistry A, 1, 5%
Journal of Materials Chemistry A
1 publication, 5%
1
2

Citations by publishers

1
2
3
4
5
6
7
Elsevier
Elsevier, 7, 35%
Elsevier
7 publications, 35%
American Chemical Society (ACS)
American Chemical Society (ACS), 4, 20%
American Chemical Society (ACS)
4 publications, 20%
Royal Society of Chemistry (RSC)
Royal Society of Chemistry (RSC), 4, 20%
Royal Society of Chemistry (RSC)
4 publications, 20%
Wiley
Wiley, 2, 10%
Wiley
2 publications, 10%
Springer Nature
Springer Nature, 1, 5%
Springer Nature
1 publication, 5%
American Physical Society (APS)
American Physical Society (APS), 1, 5%
American Physical Society (APS)
1 publication, 5%
Mineralogical Association of Canada, 1, 5%
Mineralogical Association of Canada
1 publication, 5%
1
2
3
4
5
6
7
  • We do not take into account publications that without a DOI.
  • Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
  • Statistics recalculated weekly.
Metrics
Share
Cite this
GOST |
Cite this
GOST Copy
Panin R. V. et al. Crystal Structure, Polymorphism, and Properties of the New Vanadyl Phosphate Na4VO(PO4)2 // Chemistry of Materials. 2004. Vol. 16. No. 6. pp. 1048-1055.
GOST all authors (up to 50) Copy
Panin R. V., Shpanchenko R. V., Mironov A. V., Velikodny Y. A., Antipov E. V., Hadermann J., Tarnopolsky V. A., Yaroslavtsev A. B., Kaul E. E., Geibel C. Crystal Structure, Polymorphism, and Properties of the New Vanadyl Phosphate Na4VO(PO4)2 // Chemistry of Materials. 2004. Vol. 16. No. 6. pp. 1048-1055.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/cm0351543
UR - https://doi.org/10.1021%2Fcm0351543
TI - Crystal Structure, Polymorphism, and Properties of the New Vanadyl Phosphate Na4VO(PO4)2
T2 - Chemistry of Materials
AU - Panin, Rodion V
AU - Shpanchenko, Roman V.
AU - Mironov, Andrei V.
AU - Velikodny, Yuri A.
AU - Tarnopolsky, Vasily A.
AU - Yaroslavtsev, Andrei B.
AU - Kaul, Enrique E.
AU - Antipov, Evgeny V.
AU - Hadermann, Joke
AU - Geibel, C.
PY - 2004
DA - 2004/02/10 00:00:00
PB - American Chemical Society (ACS)
SP - 1048-1055
IS - 6
VL - 16
SN - 0897-4756
SN - 1520-5002
ER -
BibTex |
Cite this
BibTex Copy
@article{2004_Panin
author = {Rodion V Panin and Roman V. Shpanchenko and Andrei V. Mironov and Yuri A. Velikodny and Vasily A. Tarnopolsky and Andrei B. Yaroslavtsev and Enrique E. Kaul and Evgeny V. Antipov and Joke Hadermann and C. Geibel},
title = {Crystal Structure, Polymorphism, and Properties of the New Vanadyl Phosphate Na4VO(PO4)2},
journal = {Chemistry of Materials},
year = {2004},
volume = {16},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021%2Fcm0351543},
number = {6},
pages = {1048--1055},
doi = {10.1021/cm0351543}
}
MLA
Cite this
MLA Copy
Panin, Rodion V., et al. “Crystal Structure, Polymorphism, and Properties of the New Vanadyl Phosphate Na4VO(PO4)2.” Chemistry of Materials, vol. 16, no. 6, Feb. 2004, pp. 1048-1055. https://doi.org/10.1021%2Fcm0351543.
Found error?