Toward the Development of New Textile/Plastic Electrochromic Cells Using Triphenylamine-Based Copolymers
Publication type: Journal Article
Publication date: 2006-07-26
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
We report the preparation and characterization of new electrochromic polymers containing a 4-butyltriphenylamine (BuTPA) unit on the main chain. All polymers were obtained through the Suzuki−Miyaura cross-coupling reaction between 4-butyl-N,N-bis((4,4,5,5-tetramethyl-1,3,2-dioxaborolan-4-phenyl)aniline) and several aryl dibromide molecules to modulate the electronic properties of the resulting copolymers. 2,5-Dibromothiophene, 2,5-dibromo(3,4-ethylenedioxythiophene), 3,6-dibromo-N-octylcarbazole, bis(6-bromo-N-octylcarbazol-3-yl), and 2,7-dibromo-3,6-dimethoxy-9,9-dihexylfluorene were used as comonomers and led to five new copolymers, PT(BuTPA), PE(BuTPA), PC(BuTPA), PCC(BuTPA), and PF(BuTPA). These polymers are readily soluble in many common organic solvents, which make them suitable for spray-coating film deposition. Electrochromic cells with the following configuration were assembled: ITO-coated glass or plastic/electrochromic polymer/gel electrolyte/ITO-coated glass or plastic or conducting textile. ...
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142
Total citations:
142
Citations from 2024:
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Beaupré S., DUMAS J., Leclerc M. Toward the Development of New Textile/Plastic Electrochromic Cells Using Triphenylamine-Based Copolymers // Chemistry of Materials. 2006. Vol. 18. No. 17. pp. 4011-4018.
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Beaupré S., DUMAS J., Leclerc M. Toward the Development of New Textile/Plastic Electrochromic Cells Using Triphenylamine-Based Copolymers // Chemistry of Materials. 2006. Vol. 18. No. 17. pp. 4011-4018.
Cite this
RIS
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TY - JOUR
DO - 10.1021/cm060407o
UR - https://doi.org/10.1021/cm060407o
TI - Toward the Development of New Textile/Plastic Electrochromic Cells Using Triphenylamine-Based Copolymers
T2 - Chemistry of Materials
AU - Beaupré, Serge
AU - DUMAS, JEAN
AU - Leclerc, Mario
PY - 2006
DA - 2006/07/26
PB - American Chemical Society (ACS)
SP - 4011-4018
IS - 17
VL - 18
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2006_Beaupré,
author = {Serge Beaupré and JEAN DUMAS and Mario Leclerc},
title = {Toward the Development of New Textile/Plastic Electrochromic Cells Using Triphenylamine-Based Copolymers},
journal = {Chemistry of Materials},
year = {2006},
volume = {18},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/cm060407o},
number = {17},
pages = {4011--4018},
doi = {10.1021/cm060407o}
}
Cite this
MLA
Copy
Beaupré, Serge, et al. “Toward the Development of New Textile/Plastic Electrochromic Cells Using Triphenylamine-Based Copolymers.” Chemistry of Materials, vol. 18, no. 17, Jul. 2006, pp. 4011-4018. https://doi.org/10.1021/cm060407o.