Structural evolution of the BiFeO3 - LaFeO3 system
Dmitriy A Rusakov
1, 2
,
K Yamaura
2
,
A. A. BELIK
1, 2
,
Gustaaf Van Tendeloo
3
,
Eiji Takayama-Muromachi
2
Publication type: Journal Article
Publication date: 2010-12-23
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The (1 − x)BiFeO3−xLaFeO3 system has been investigated and characterized by room-temperature and high-temperature laboratory and synchrotron powder X-ray diffraction, electron diffraction, high-resolution transmission electron microscopy, differential scanning calorimetry, and magnetization measurements. At room temperature, the ferroelectric R3c phase is observed for 0.0 ≤ x ≤ 0.10. The PbZrO3-related √2ap × 2√2ap × 4ap superstructure (where ap is the parameter of the cubic perovskite subcell) is observed for Bi0.82La0.18FeO3, while an incommensurately modulated phase is formed for 0.19 ≤ x ≤ 0.30 with the √2ap × 2ap × √2ap basic unit cell. The GdFeO3-type phase with space group Pnma (√2ap × 2ap × √2ap) is stable at 0.50 ≤ x ≤ 1. Bi0.82La0.18FeO3 has no detectable homogeneity range (space group Pnam, a = 5.6004(1) A, b = 11.2493(3) A, c = 15.6179(3) A). The incommensurately modulated Bi0.75La0.25FeO3 structure was solved from synchrotron X-ray powder diffraction data (Imma(00γ)s00 superspace group, a = 5...
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172
Total citations:
172
Citations from 2024:
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(7.56%)
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GOST
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Rusakov D. A. et al. Structural evolution of the BiFeO3 - LaFeO3 system // Chemistry of Materials. 2010. Vol. 23. No. 2. pp. 285-292.
GOST all authors (up to 50)
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Rusakov D. A., Abakumov A. M., Yamaura K., BELIK A. A., Van Tendeloo G., Takayama-Muromachi E. Structural evolution of the BiFeO3 - LaFeO3 system // Chemistry of Materials. 2010. Vol. 23. No. 2. pp. 285-292.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/cm1030975
UR - https://doi.org/10.1021/cm1030975
TI - Structural evolution of the BiFeO3 - LaFeO3 system
T2 - Chemistry of Materials
AU - Rusakov, Dmitriy A
AU - Abakumov, Artem M.
AU - Yamaura, K
AU - BELIK, A. A.
AU - Van Tendeloo, Gustaaf
AU - Takayama-Muromachi, Eiji
PY - 2010
DA - 2010/12/23
PB - American Chemical Society (ACS)
SP - 285-292
IS - 2
VL - 23
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2010_Rusakov,
author = {Dmitriy A Rusakov and Artem M. Abakumov and K Yamaura and A. A. BELIK and Gustaaf Van Tendeloo and Eiji Takayama-Muromachi},
title = {Structural evolution of the BiFeO3 - LaFeO3 system},
journal = {Chemistry of Materials},
year = {2010},
volume = {23},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/cm1030975},
number = {2},
pages = {285--292},
doi = {10.1021/cm1030975}
}
Cite this
MLA
Copy
Rusakov, Dmitriy A., et al. “Structural evolution of the BiFeO3 - LaFeO3 system.” Chemistry of Materials, vol. 23, no. 2, Dec. 2010, pp. 285-292. https://doi.org/10.1021/cm1030975.
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