Chemistry of Materials

, volume 25 , issue 21 , pages 4387-4395

Incommensurate Modulation and Luminescence in the CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors

Vladimir Alexei Morozov ^{1, 2}

Anne Bertha ¹

Katrien W Meert ^{3, 4}

Senne Van Rompaey ¹

Dmitry Batuk ¹

Gerardo T. Martinez ¹

Sandra Van Aert ¹

Philippe F Smet ^{3, 4}

Maria V Raskina ²

Dirk Poelman ^{3, 4}

Artem M. Abakumov ¹

Joke Hadermann ¹

Hide authors affiliations Show authors affiliations: 4 affiliations

EMAT, University of Antwerp, Groenenborgerlaan 171, Antwerp B-2020, Belgium |

Chemistry Department, Moscow State University, 119991 Moscow, Russia |

Lumilab, Department of Solid State Sciences, Ghent University, B-9000 Ghent, Belgium |

⁴

Center for Nano- and Biophotonics (NB-Photonics), Ghent University, B-9000 Ghent, Belgium |

Publication type: Journal Article

Publication date: 2013-10-11

American Chemical Society (ACS)

Chemistry of Materials

scimago Q1

wos Q1

SJR: 2.065

CiteScore: 12.0

Impact factor: 7.0

ISSN: 08974756, 15205002

DOI: 10.1021/cm402729r

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Materials Chemistry

General Chemistry

General Chemical Engineering

Abstract

Scheelite related compounds (A′,A″)n[(B′,B″)O4]m with B′, B″ = W and/or Mo are promising new light-emitting materials for photonic applications, including phosphor converted LEDs (light-emitting diodes). In this paper, the creation and ordering of A-cation vacancies and the effect of cation substitutions in the scheelite-type framework are investigated as a factor for controlling the scheelite-type structure and luminescent properties. CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) solid solutions with scheelite-type structure were synthesized by a solid state method, and their structures were investigated using a combination of transmission electron microscopy techniques and powder X-ray diffraction. Within this series all complex molybdenum oxides have (3 + 2)D incommensurately modulated structures with superspace group I41/a(α,β,0)00(−β,α,0)00, while the structures of all tungstates are (3 + 1)D incommensurately modulated with superspace group I2/b(αβ0)00. In both cases the modulation arises ...

Found

5 citations

Aleksandrovsky Aleksandr

PhD in Physics and Mathematics

164 publications, 3 244 citations, 17 reviews

h-index: 29

Kirensky Institute of Physics of the Siberian Branch of the Russian Academy of Sciences

5 citations

Oreshonkov Aleksandr

🤝

PhD in Physics and Mathematics

92 publications, 2 341 citations, 27 reviews

h-index: 24

Kirensky Institute of Physics of the Siberian Branch of the Russian Academy of Sciences

Research interests

Infrared spectroscopy

Raman spectroscopy

3 citations

Deyneko Dina

PhD in Chemistry

118 publications, 1 106 citations, 56 reviews

h-index: 18

Lomonosov Moscow State University

Nanomaterials Research Centre of the Kola Science Centre of the Russian Academy of Sciences

Research interests

Luminescent materials

Rare-earth elements

1 citation

Morozov Anatolii

PhD in Chemistry, lecturer

47 publications, 1 469 citations

h-index: 17

Skolkovo Institute of Science and Technology

Lithium-ion batteries

Solid state chemistry

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GOST |

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GOST Copy

Morozov V. A. et al. Incommensurate Modulation and Luminescence in the CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors // Chemistry of Materials. 2013. Vol. 25. No. 21. pp. 4387-4395.

GOST all authors (up to 50) Copy

Morozov V. A., Bertha A., Meert K. W., Van Rompaey S., Batuk D., Martinez G. T., Van Aert S., Smet P. F., Raskina M. V., Poelman D., Abakumov A. M., Hadermann J. Incommensurate Modulation and Luminescence in the CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors // Chemistry of Materials. 2013. Vol. 25. No. 21. pp. 4387-4395.

RIS |

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RIS Copy

TY - JOUR

DO - 10.1021/cm402729r

UR - https://doi.org/10.1021/cm402729r

TI - Incommensurate Modulation and Luminescence in the CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors

T2 - Chemistry of Materials

AU - Morozov, Vladimir Alexei

AU - Bertha, Anne

AU - Meert, Katrien W

AU - Van Rompaey, Senne

AU - Batuk, Dmitry

AU - Martinez, Gerardo T.

AU - Van Aert, Sandra

AU - Smet, Philippe F

AU - Raskina, Maria V

AU - Poelman, Dirk

AU - Abakumov, Artem M.

AU - Hadermann, Joke

PY - 2013

DA - 2013/10/11

PB - American Chemical Society (ACS)

SP - 4387-4395

IS - 21

VL - 25

SN - 0897-4756

SN - 1520-5002

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2013_Morozov,

author = {Vladimir Alexei Morozov and Anne Bertha and Katrien W Meert and Senne Van Rompaey and Dmitry Batuk and Gerardo T. Martinez and Sandra Van Aert and Philippe F Smet and Maria V Raskina and Dirk Poelman and Artem M. Abakumov and Joke Hadermann},

title = {Incommensurate Modulation and Luminescence in the CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors},

journal = {Chemistry of Materials},

year = {2013},

volume = {25},

publisher = {American Chemical Society (ACS)},

month = {oct},

url = {https://doi.org/10.1021/cm402729r},

number = {21},

pages = {4387--4395},

doi = {10.1021/cm402729r}

}

MLA

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MLA Copy

Morozov, Vladimir Alexei, et al. “Incommensurate Modulation and Luminescence in the CaGd2(1–x)Eu2x(MoO4)4(1–y)(WO4)4y (0 ≤ x ≤ 1, 0 ≤ y ≤ 1) Red Phosphors.” Chemistry of Materials, vol. 25, no. 21, Oct. 2013, pp. 4387-4395. https://doi.org/10.1021/cm402729r.

Publisher

American Chemical Society (ACS)

Journal

Chemistry of Materials

scimago Q1

wos Q1

SJR

2.065

CiteScore

12.0

Impact factor

7.0

ISSN

08974756 (Print)

15205002 (Electronic)

Profiles

Artem M Abakumov