Influence of the structure on the properties of Nax Eu y (MoO4 )z red phosphors
Vladimir Alexei Morozov
1, 2
,
Semen Z Shmurak
3
,
Aleksander P Kiselev
3
,
Oleg Lebedev
4
,
Nicolas Gauquelin
2
,
J. Verbeeck
2
,
Joke Hadermann
2
,
Gustaaf Van Tendeloo
2
4
Laboratoire
CRISMAT, UMR 6508 CNRS ENSICAEN, 6bd Maréchal Juin, 14050 Caen, France
|
Publication type: Journal Article
Publication date: 2014-05-09
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Scheelite related compounds (A′,A″)n[(B′,B″)O4]m with B′, B″ = W and/or Mo are promising new materials for red phosphors in pc-WLEDs (phosphor-converted white-light-emitting-diode) and solid-state lasers. Cation substitution in CaMoO4 of Ca2+ by the combination of Na+ and Eu3+, with the creation of A cation vacancies, has been investigated as a factor for controlling the scheelite-type structure and the luminescent properties. Na5Eu(MoO4)4 and NaxEu3+(2–x)/3□(1–2x)/3MoO4 (0.138 ≤ x ≤ 0.5) phases with a scheelite-type structure were synthesized by the solid state method; their structural characteristics were investigated using transmission electron microscopy. Contrary to powder synchrotron X-ray diffraction before, the study by electron diffraction and high resolution transmission electron microscopy in this paper revealed that Na0.286Eu0.571MoO4 has a (3 + 2)D incommensurately modulated structure and that (3 + 2)D incommensurately modulated domains are present in Na0.200Eu0.600MoO4. It also confirmed the...
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57
Total citations:
57
Citations from 2024:
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(7.01%)
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GOST
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Morozov V. A. et al. Influence of the structure on the properties of NaxEu y(MoO4)z red phosphors // Chemistry of Materials. 2014. Vol. 26. No. 10. pp. 3238-3248.
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Morozov V. A., Lazoryak B. I., Shmurak S. Z., Kiselev A. P., Lebedev O., Gauquelin N., Verbeeck J., Hadermann J., Van Tendeloo G. Influence of the structure on the properties of NaxEu y(MoO4)z red phosphors // Chemistry of Materials. 2014. Vol. 26. No. 10. pp. 3238-3248.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/cm500966g
UR - https://doi.org/10.1021/cm500966g
TI - Influence of the structure on the properties of NaxEu y(MoO4)z red phosphors
T2 - Chemistry of Materials
AU - Morozov, Vladimir Alexei
AU - Lazoryak, Bogdan I.
AU - Shmurak, Semen Z
AU - Kiselev, Aleksander P
AU - Lebedev, Oleg
AU - Gauquelin, Nicolas
AU - Verbeeck, J.
AU - Hadermann, Joke
AU - Van Tendeloo, Gustaaf
PY - 2014
DA - 2014/05/09
PB - American Chemical Society (ACS)
SP - 3238-3248
IS - 10
VL - 26
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
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@article{2014_Morozov,
author = {Vladimir Alexei Morozov and Bogdan I. Lazoryak and Semen Z Shmurak and Aleksander P Kiselev and Oleg Lebedev and Nicolas Gauquelin and J. Verbeeck and Joke Hadermann and Gustaaf Van Tendeloo},
title = {Influence of the structure on the properties of NaxEu y(MoO4)z red phosphors},
journal = {Chemistry of Materials},
year = {2014},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/cm500966g},
number = {10},
pages = {3238--3248},
doi = {10.1021/cm500966g}
}
Cite this
MLA
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Morozov, Vladimir Alexei, et al. “Influence of the structure on the properties of NaxEu y(MoO4)z red phosphors.” Chemistry of Materials, vol. 26, no. 10, May. 2014, pp. 3238-3248. https://doi.org/10.1021/cm500966g.