Chemistry of Materials, volume 26, issue 16, pages 4741-4749
Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes
1
Department
of Mechanical
Engineering, University of Colorado Boulder, Boulder, Colorado 80309, United States
|
2
Grupo Crescimento
de Cristais
e Materiais Cerâmicos, Instituto de Física de São
Carlos, Universidade de São Paulo, 13560-970 São
Carlos, SP, Brazil
|
Publication type: Journal Article
Publication date: 2014-08-08
Journal:
Chemistry of Materials
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 8.6
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
Herein, we report a study on the structural and thermodynamic effects that cation size disparity may have in NASICON-type solid solutions. A sol–gel procedure was used to synthesize two new NASICON-type lithium-ion conductors with nominal compositions LiGe2–ySny(PO4)3 and Li1+xAlxGe2–y–(1/2)xSny–(1/2)x(PO4)3. The effect of tin substitution on structure and lithium-ion conductivity was studied with powder X-ray diffraction, Raman spectroscopy, and dielectric spectroscopy. It is found that, although increased unit-cell dimensions derived from X-ray data suggest that tin incorporation should open the conduction bottleneck regions and improve conductivity, a decrease in conductivity is observed. Analysis of the electrical data shows that the conduction activation energy is comprised of contributions from carrier motion and generation, the latter accounting for up to 20% of the total activation energy. This result, currently unreported for NASICON-type materials, is correlated with local structural distortions...
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Francisco B. E., Stoldt C. R., Mpeko J. C. Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes // Chemistry of Materials. 2014. Vol. 26. No. 16. pp. 4741-4749.
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Francisco B. E., Stoldt C. R., Mpeko J. C. Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes // Chemistry of Materials. 2014. Vol. 26. No. 16. pp. 4741-4749.
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TY - JOUR
DO - 10.1021/cm5013872
UR - https://doi.org/10.1021/cm5013872
TI - Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes
T2 - Chemistry of Materials
AU - Francisco, Brian E
AU - Stoldt, Conrad R.
AU - Mpeko, Jean Claude
PY - 2014
DA - 2014/08/08 00:00:00
PB - American Chemical Society (ACS)
SP - 4741-4749
IS - 16
VL - 26
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2014_Francisco,
author = {Brian E Francisco and Conrad R. Stoldt and Jean Claude Mpeko},
title = {Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes},
journal = {Chemistry of Materials},
year = {2014},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {aug},
url = {https://doi.org/10.1021/cm5013872},
number = {16},
pages = {4741--4749},
doi = {10.1021/cm5013872}
}
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MLA
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Francisco, Brian E., et al. “Lithium-Ion Trapping from Local Structural Distortions in Sodium Super Ionic Conductor (NASICON) Electrolytes.” Chemistry of Materials, vol. 26, no. 16, Aug. 2014, pp. 4741-4749. https://doi.org/10.1021/cm5013872.