Crystal Structure and Luminescent Properties of R2–xEux(MoO4)3 (R = Gd, Sm) Red Phosphors
Vladimir Alexei Morozov
1, 2
,
Maria V Raskina
1
,
Katrien W Meert
3, 4
,
Katleen Korthout
3, 4
,
Philippe F Smet
3, 4
,
Dirk Poelman
3, 4
,
Nicolas Gauquelin
2
,
J. Verbeeck
2
,
Artem M. Abakumov
1, 2
,
2
Publication type: Journal Article
Publication date: 2014-12-12
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The R2(MoO4)3 (R = rare earth elements) molybdates doped with Eu3+ cations are interesting red-emitting materials for display and solid-state lighting applications. The structure and luminescent properties of the R2–xEux(MoO4)3 (R = Gd, Sm) solid solutions have been investigated as a function of chemical composition and preparation conditions. Monoclinic (α) and orthorhombic (β′) R2–xEux(MoO4)3 (R = Gd, Sm; 0 ≤ x ≤ 2) modifications were prepared by solid-state reaction, and their structures were investigated using synchrotron powder X-ray diffraction and transmission electron microscopy. The pure orthorhombic β′-phases could be synthesized only by quenching from high temperature to room temperature for Gd2–xEux(MoO4)3 in the Eu3+-rich part (x > 1) and for all Sm2–xEux(MoO4)3 solid solutions. The transformation from the α-phase to the β′-phase results in a notable increase (∼24%) of the unit cell volume for all R2–xEux(MoO4)3 (R = Sm, Gd) solid solutions. The luminescent properties of all R2–xEux(MoO4)3 (R...
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28
Total citations:
28
Citations from 2024:
4
(14%)
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GOST
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Morozov V. A. et al. Crystal Structure and Luminescent Properties of R2–xEux(MoO4)3 (R = Gd, Sm) Red Phosphors // Chemistry of Materials. 2014. Vol. 26. No. 24. pp. 7124-7136.
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Morozov V. A., Raskina M. V., Lazoryak B. I., Meert K. W., Korthout K., Smet P. F., Poelman D., Gauquelin N., Verbeeck J., Abakumov A. M., Hadermann J. Crystal Structure and Luminescent Properties of R2–xEux(MoO4)3 (R = Gd, Sm) Red Phosphors // Chemistry of Materials. 2014. Vol. 26. No. 24. pp. 7124-7136.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/cm503720s
UR - https://doi.org/10.1021/cm503720s
TI - Crystal Structure and Luminescent Properties of R2–xEux(MoO4)3 (R = Gd, Sm) Red Phosphors
T2 - Chemistry of Materials
AU - Morozov, Vladimir Alexei
AU - Raskina, Maria V
AU - Lazoryak, Bogdan I.
AU - Meert, Katrien W
AU - Korthout, Katleen
AU - Smet, Philippe F
AU - Poelman, Dirk
AU - Gauquelin, Nicolas
AU - Verbeeck, J.
AU - Abakumov, Artem M.
AU - Hadermann, Joke
PY - 2014
DA - 2014/12/12
PB - American Chemical Society (ACS)
SP - 7124-7136
IS - 24
VL - 26
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2014_Morozov,
author = {Vladimir Alexei Morozov and Maria V Raskina and Bogdan I. Lazoryak and Katrien W Meert and Katleen Korthout and Philippe F Smet and Dirk Poelman and Nicolas Gauquelin and J. Verbeeck and Artem M. Abakumov and Joke Hadermann},
title = {Crystal Structure and Luminescent Properties of R2–xEux(MoO4)3 (R = Gd, Sm) Red Phosphors},
journal = {Chemistry of Materials},
year = {2014},
volume = {26},
publisher = {American Chemical Society (ACS)},
month = {dec},
url = {https://doi.org/10.1021/cm503720s},
number = {24},
pages = {7124--7136},
doi = {10.1021/cm503720s}
}
Cite this
MLA
Copy
Morozov, Vladimir Alexei, et al. “Crystal Structure and Luminescent Properties of R2–xEux(MoO4)3 (R = Gd, Sm) Red Phosphors.” Chemistry of Materials, vol. 26, no. 24, Dec. 2014, pp. 7124-7136. https://doi.org/10.1021/cm503720s.
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