Tetrahedral chain order in the Sr2 Fe2 O5 brownmillerite
Hans D'Hondt
1
,
Joke Hadermann
1
,
Anna S Kalyuzhnaya
1
,
Marina G Rozova
1
,
Gustaaf Van Tendeloo
1
Publication type: Journal Article
Publication date: 2008-10-25
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The crystal structure of the Sr2Fe2O5 brownmillerite has been investigated using electron diffraction and high resolution electron microscopy. The Sr2Fe2O5 structure demonstrates two-dimensional order: the tetrahedral chains with two mirror-related configurations (L and R) are arranged within the tetrahedral layers according to the −L−R−L−R− sequence, and the layers themselves are displaced with respect to each other over 1/2[111] or 1/2[111] vectors of the brownmillerite unit cell, resulting in different ordered stacking variants. A unified superspace model is constructed for ordered stacking sequences in brownmillerites based on the average brownmillerite structure with a = 5.5298(4)A, b = 15.5875(12)A, c = 5.6687(4)A, and (3 + 1)-dimensional superspace group I2/m(0βγ)0s, q = βb* + γc*, 0 ≤ β ≤ 1/2, 0 ≤ γ ≤ 1.
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94
Total citations:
94
Citations from 2024:
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(13%)
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GOST
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D'Hondt H. et al. Tetrahedral chain order in the Sr2Fe2O5 brownmillerite // Chemistry of Materials. 2008. Vol. 20. No. 22. pp. 7188-7194.
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D'Hondt H., Abakumov A. M., Hadermann J., Kalyuzhnaya A. S., Rozova M. G., Antipov E. V., Van Tendeloo G. Tetrahedral chain order in the Sr2Fe2O5 brownmillerite // Chemistry of Materials. 2008. Vol. 20. No. 22. pp. 7188-7194.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/cm801723b
UR - https://pubs.acs.org/doi/10.1021/cm801723b
TI - Tetrahedral chain order in the Sr2Fe2O5 brownmillerite
T2 - Chemistry of Materials
AU - D'Hondt, Hans
AU - Abakumov, Artem M.
AU - Hadermann, Joke
AU - Kalyuzhnaya, Anna S
AU - Rozova, Marina G
AU - Antipov, Evgeny V.
AU - Van Tendeloo, Gustaaf
PY - 2008
DA - 2008/10/25
PB - American Chemical Society (ACS)
SP - 7188-7194
IS - 22
VL - 20
SN - 0897-4756
SN - 1520-5002
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2008_D'Hondt,
author = {Hans D'Hondt and Artem M. Abakumov and Joke Hadermann and Anna S Kalyuzhnaya and Marina G Rozova and Evgeny V. Antipov and Gustaaf Van Tendeloo},
title = {Tetrahedral chain order in the Sr2Fe2O5 brownmillerite},
journal = {Chemistry of Materials},
year = {2008},
volume = {20},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://pubs.acs.org/doi/10.1021/cm801723b},
number = {22},
pages = {7188--7194},
doi = {10.1021/cm801723b}
}
Cite this
MLA
Copy
D'Hondt, Hans, et al. “Tetrahedral chain order in the Sr2Fe2O5 brownmillerite.” Chemistry of Materials, vol. 20, no. 22, Oct. 2008, pp. 7188-7194. https://pubs.acs.org/doi/10.1021/cm801723b.
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