Incommensurate crystallographic shear structures and magnetic properties of the cation deficient perovskite (Sr0.6 Pb0.18 )(Fe 0.75 Mn0.25 )O2.29
1
Laboratoire CRISMAT-ENSICAEN, Bd du Maréchal Juin-14050 CAEN cedex, France
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Publication type: Journal Article
Publication date: 2010-01-19
scimago Q1
wos Q1
SJR: 2.065
CiteScore: 12.0
Impact factor: 7.0
ISSN: 08974756, 15205002
Materials Chemistry
General Chemistry
General Chemical Engineering
Abstract
The origin of the incommensurability in the crystallographic shear (CS) structure of the ferri-Manganite (Sr0.61Pb0.18)(Fe0.75Mn0.25)O2.29, related to the cation deficient perovskite, has been determined by careful analysis of the boundaries between the two variants constituting the phasoid. High Resolution Electron Microscopy/HAADF-STEM images allow the structural mechanisms to be understood through the presence of structural units common to both phases, responsible of the incommensurate character observed in the electron diffraction patterns. The structural analysis allows for identifying different types of CS phases in the Pb−Sr−Fe(Mn)−O diagram and shows that the stabilization of the six-sided tunnels requires a higher A/B cationic ratio. A description of these phases is proposed through simple structural building units (SBU), based on chains of octahedra bordered by two pyramids. The (Sr0.61Pb0.18)(Fe0.75Mn0.25)O2.29 CS compound exhibits a strong antiferromagnetic and insulating behavior, similar to ...
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Malo S. et al. Incommensurate crystallographic shear structures and magnetic properties of the cation deficient perovskite (Sr0.6Pb0.18)(Fe 0.75Mn0.25)O2.29 // Chemistry of Materials. 2010. Vol. 22. No. 5. pp. 1788-1797.
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Malo S., Lepoittevin C., Pérez O., Hébert S., Van Tendeloo G., Hervieu M. Incommensurate crystallographic shear structures and magnetic properties of the cation deficient perovskite (Sr0.6Pb0.18)(Fe 0.75Mn0.25)O2.29 // Chemistry of Materials. 2010. Vol. 22. No. 5. pp. 1788-1797.
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TY - JOUR
DO - 10.1021/cm903288s
UR - https://doi.org/10.1021/cm903288s
TI - Incommensurate crystallographic shear structures and magnetic properties of the cation deficient perovskite (Sr0.6Pb0.18)(Fe 0.75Mn0.25)O2.29
T2 - Chemistry of Materials
AU - Malo, S.
AU - Lepoittevin, C.
AU - Pérez, O
AU - Hébert, Sylvie
AU - Van Tendeloo, G.
AU - Hervieu, M.
PY - 2010
DA - 2010/01/19
PB - American Chemical Society (ACS)
SP - 1788-1797
IS - 5
VL - 22
SN - 0897-4756
SN - 1520-5002
ER -
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@article{2010_Malo,
author = {S. Malo and C. Lepoittevin and O Pérez and Sylvie Hébert and G. Van Tendeloo and M. Hervieu},
title = {Incommensurate crystallographic shear structures and magnetic properties of the cation deficient perovskite (Sr0.6Pb0.18)(Fe 0.75Mn0.25)O2.29},
journal = {Chemistry of Materials},
year = {2010},
volume = {22},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/cm903288s},
number = {5},
pages = {1788--1797},
doi = {10.1021/cm903288s}
}
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MLA
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Malo, S., et al. “Incommensurate crystallographic shear structures and magnetic properties of the cation deficient perovskite (Sr0.6Pb0.18)(Fe 0.75Mn0.25)O2.29.” Chemistry of Materials, vol. 22, no. 5, Jan. 2010, pp. 1788-1797. https://doi.org/10.1021/cm903288s.