, volume 3 , issue 2 , pages 139-149

Pt/Pd/Fe Trimetallic Nanoparticle Produced via Reverse Micelle Technique: Synthesis, Characterization, and Its Use as an Efficient Catalyst for Reductive Hydrodehalogenation of Aryl and Aliphatic Halides under Mild Conditions

Reza Abazari ¹

Felora Heshmatpour ¹

Saeed Balalaie ¹

Hide authors affiliations Show authors affiliations: 1 affiliation

Department of chemistry, Faculty of Science, K.N.Toosi University of Technology, P.O. Box 16315-1618, Tehran, 15418, Islamic Republic of Iran |

Publication type: Journal Article

Publication date: 2012-12-31

American Chemical Society (ACS)

ACS Catalysis

scimago Q1

wos Q1

SJR: 3.782

CiteScore: 19.5

Impact factor: 13.1

ISSN: 21555435

DOI: 10.1021/cs300507a

Copy DOI

General Chemistry

Catalysis

Abstract

The Pt/Pd/Fe trimetallic nanoparticle (Pt/Pd/Fe T-NP) was prepared using a water-in-oil microemulsion system of water/AOT/isooctane at room temperature. This nanoparticle (NP) was physically characterized by field emission scanning electron microscopy (FE-SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray fluorescence (XRF) analyses. The said NP was used as catalyst for hydrodehalogenation (HDH) of halogenated organic compounds (HOCs), and its capability in hydrodechlorination (HDC) of chlorobenzene was compared with Pt/Pd, Pt/Fe, and Pd/Fe bimetallic nanoparticles (B-NPs) synthesized via the same method. The formation of mixed Pt/Pd/Fe ensembles results in an enhanced overall activity and reusability of HDC reaction, compared with Pd/Fe catalyst which acted as the best B-NP. Recycling experiments were examined for HDC of chlorobenzene. To get a maximum conversion of HDC, the reaction parameters like the effect of solvent, amounts of catalyst and ammonium formate were optimized. According to the results, HOCs, including electron-withdrawing and electron-donating substrates, were reduced smoothly. Finally, a mechanism for HDH reaction on the Pt/Pd/Fe catalyst surface was proposed.

Found

1 citation

Petrukhina N

37 publications, 533 citations

h-index: 13

Top-30

Journals

	1 2 3 4 5 6
RSC Advances	RSC Advances, 6, 10.34% RSC Advances 6 publications, 10.34%
Applied Catalysis A: General	Applied Catalysis A: General, 2, 3.45% Applied Catalysis A: General 2 publications, 3.45%
Journal of Cleaner Production	Journal of Cleaner Production, 2, 3.45% Journal of Cleaner Production 2 publications, 3.45%
ACS applied materials & interfaces	ACS applied materials & interfaces, 2, 3.45% ACS applied materials & interfaces 2 publications, 3.45%
Industrial & Engineering Chemistry Research	Industrial & Engineering Chemistry Research, 2, 3.45% Industrial & Engineering Chemistry Research 2 publications, 3.45%
Catalysis Science and Technology	Catalysis Science and Technology, 2, 3.45% Catalysis Science and Technology 2 publications, 3.45%
New Journal of Chemistry	New Journal of Chemistry, 2, 3.45% New Journal of Chemistry 2 publications, 3.45%
International Journal of Molecular Sciences	International Journal of Molecular Sciences, 1, 1.72% International Journal of Molecular Sciences 1 publication, 1.72%
Polymers	Polymers, 1, 1.72% Polymers 1 publication, 1.72%
Journal of Cluster Science	Journal of Cluster Science, 1, 1.72% Journal of Cluster Science 1 publication, 1.72%
Analytical and Bioanalytical Chemistry	Analytical and Bioanalytical Chemistry, 1, 1.72% Analytical and Bioanalytical Chemistry 1 publication, 1.72%
Scientific Reports	Scientific Reports, 1, 1.72% Scientific Reports 1 publication, 1.72%
Journal of Sol-Gel Science and Technology	Journal of Sol-Gel Science and Technology, 1, 1.72% Journal of Sol-Gel Science and Technology 1 publication, 1.72%
Catalysis Letters	Catalysis Letters, 1, 1.72% Catalysis Letters 1 publication, 1.72%
Nature Catalysis	Nature Catalysis, 1, 1.72% Nature Catalysis 1 publication, 1.72%
Journal of Materials Research	Journal of Materials Research, 1, 1.72% Journal of Materials Research 1 publication, 1.72%
Journal of Energy Chemistry	Journal of Energy Chemistry, 1, 1.72% Journal of Energy Chemistry 1 publication, 1.72%
Journal of Fluorine Chemistry	Journal of Fluorine Chemistry, 1, 1.72% Journal of Fluorine Chemistry 1 publication, 1.72%
Journal of the Taiwan Institute of Chemical Engineers	Journal of the Taiwan Institute of Chemical Engineers, 1, 1.72% Journal of the Taiwan Institute of Chemical Engineers 1 publication, 1.72%
Chinese Chemical Letters	Chinese Chemical Letters, 1, 1.72% Chinese Chemical Letters 1 publication, 1.72%
Journal of Organometallic Chemistry	Journal of Organometallic Chemistry, 1, 1.72% Journal of Organometallic Chemistry 1 publication, 1.72%
Tetrahedron	Tetrahedron, 1, 1.72% Tetrahedron 1 publication, 1.72%
Journal of Molecular Liquids	Journal of Molecular Liquids, 1, 1.72% Journal of Molecular Liquids 1 publication, 1.72%
Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy	Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy, 1, 1.72% Spectrochimica Acta - Part A: Molecular and Biomolecular Spectroscopy 1 publication, 1.72%
Environmental Nanotechnology, Monitoring and Management	Environmental Nanotechnology, Monitoring and Management, 1, 1.72% Environmental Nanotechnology, Monitoring and Management 1 publication, 1.72%
Chemical Engineering Journal	Chemical Engineering Journal, 1, 1.72% Chemical Engineering Journal 1 publication, 1.72%
Ultrasonics Sonochemistry	Ultrasonics Sonochemistry, 1, 1.72% Ultrasonics Sonochemistry 1 publication, 1.72%
Advanced Engineering Materials	Advanced Engineering Materials, 1, 1.72% Advanced Engineering Materials 1 publication, 1.72%
Applied Organometallic Chemistry	Applied Organometallic Chemistry, 1, 1.72% Applied Organometallic Chemistry 1 publication, 1.72%
ChemistrySelect	ChemistrySelect, 1, 1.72% ChemistrySelect 1 publication, 1.72%
	1 2 3 4 5 6

Publishers

	2 4 6 8 10 12 14 16
Elsevier	Elsevier, 16, 27.59% Elsevier 16 publications, 27.59%
Royal Society of Chemistry (RSC)	Royal Society of Chemistry (RSC), 14, 24.14% Royal Society of Chemistry (RSC) 14 publications, 24.14%
Springer Nature	Springer Nature, 8, 13.79% Springer Nature 8 publications, 13.79%
American Chemical Society (ACS)	American Chemical Society (ACS), 7, 12.07% American Chemical Society (ACS) 7 publications, 12.07%
Wiley	Wiley, 4, 6.9% Wiley 4 publications, 6.9%
MDPI	MDPI, 3, 5.17% MDPI 3 publications, 5.17%
Taylor & Francis	Taylor & Francis, 2, 3.45% Taylor & Francis 2 publications, 3.45%
Taiwan Institute of Chemical Engineers	Taiwan Institute of Chemical Engineers, 1, 1.72% Taiwan Institute of Chemical Engineers 1 publication, 1.72%
Pleiades Publishing	Pleiades Publishing, 1, 1.72% Pleiades Publishing 1 publication, 1.72%
Walter de Gruyter	Walter de Gruyter, 1, 1.72% Walter de Gruyter 1 publication, 1.72%
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii	Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii, 1, 1.72% Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii 1 publication, 1.72%
	2 4 6 8 10 12 14 16

We do not take into account publications without a DOI.
Statistics recalculated weekly.

Are you a researcher?

Create a profile to get free access to personal recommendations for colleagues and new articles.

Metrics

Cite this

GOST |

Cite this

GOST Copy

Abazari R., Heshmatpour F., Balalaie S. Pt/Pd/Fe Trimetallic Nanoparticle Produced via Reverse Micelle Technique: Synthesis, Characterization, and Its Use as an Efficient Catalyst for Reductive Hydrodehalogenation of Aryl and Aliphatic Halides under Mild Conditions // ACS Catalysis. 2012. Vol. 3. No. 2. pp. 139-149.

GOST all authors (up to 50) Copy

RIS |

Cite this

RIS Copy

TY - JOUR

DO - 10.1021/cs300507a

UR - https://doi.org/10.1021/cs300507a

TI - Pt/Pd/Fe Trimetallic Nanoparticle Produced via Reverse Micelle Technique: Synthesis, Characterization, and Its Use as an Efficient Catalyst for Reductive Hydrodehalogenation of Aryl and Aliphatic Halides under Mild Conditions

T2 - ACS Catalysis

AU - Abazari, Reza

AU - Heshmatpour, Felora

AU - Balalaie, Saeed

PY - 2012

DA - 2012/12/31

PB - American Chemical Society (ACS)

SP - 139-149

IS - 2

VL - 3

SN - 2155-5435

ER -

BibTex |

Cite this

BibTex (up to 50 authors) Copy

@article{2012_Abazari,

author = {Reza Abazari and Felora Heshmatpour and Saeed Balalaie},

title = {Pt/Pd/Fe Trimetallic Nanoparticle Produced via Reverse Micelle Technique: Synthesis, Characterization, and Its Use as an Efficient Catalyst for Reductive Hydrodehalogenation of Aryl and Aliphatic Halides under Mild Conditions},

journal = {ACS Catalysis},

year = {2012},

volume = {3},

publisher = {American Chemical Society (ACS)},

month = {dec},

url = {https://doi.org/10.1021/cs300507a},

number = {2},

pages = {139--149},

doi = {10.1021/cs300507a}

}

MLA

Cite this

MLA Copy

Abazari, Reza, et al. “Pt/Pd/Fe Trimetallic Nanoparticle Produced via Reverse Micelle Technique: Synthesis, Characterization, and Its Use as an Efficient Catalyst for Reductive Hydrodehalogenation of Aryl and Aliphatic Halides under Mild Conditions.” ACS Catalysis, vol. 3, no. 2, Dec. 2012, pp. 139-149. https://doi.org/10.1021/cs300507a.

Publisher

American Chemical Society (ACS)

Journal

ACS Catalysis

scimago Q1

wos Q1

SJR

3.782

CiteScore

19.5

Impact factor

13.1

ISSN

21555435 (Print, Electronic)