volume 28 issue 9 pages 1648-1653

Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity

Andrea Zanardo
Rino A. Michelin
Francesco Pinna
Giorgio Strukul
Publication typeJournal Article
Publication date1989-05-01
scimago Q1
wos Q1
SJR0.958
CiteScore7.4
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
The epoxidation fo 1-octene with H 2 O 2 has been examined by using as catalysts a homologous class of 10 (diphosphine)Pt-(CF 3 )(solv) + and 10 (diphosphine)Pt(CF 3 )(OH) type complexes, where the diphosphine has been systematically varied. All diphosphines contain two-PPh 2 groups but differ in the hydrocarbon chain linking together the two phosphorus atoms. The epoxidation reaction experimental conditions have been chosen in order to study the effect of the metal-diphosphine ring size and ring shape on the catalytic activity. It appears that diphosphine complexes with rigid, five-membered chelate rings prove to be the best catalysts
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GOST Copy
Zanardo A. et al. Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity // Inorganic Chemistry. 1989. Vol. 28. No. 9. pp. 1648-1653.
GOST all authors (up to 50) Copy
Zanardo A., Michelin R. A., Pinna F., Strukul G. Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity // Inorganic Chemistry. 1989. Vol. 28. No. 9. pp. 1648-1653.
RIS |
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RIS Copy
TY - JOUR
DO - 10.1021/ic00308a010
UR - https://doi.org/10.1021/ic00308a010
TI - Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity
T2 - Inorganic Chemistry
AU - Zanardo, Andrea
AU - Michelin, Rino A.
AU - Pinna, Francesco
AU - Strukul, Giorgio
PY - 1989
DA - 1989/05/01
PB - American Chemical Society (ACS)
SP - 1648-1653
IS - 9
VL - 28
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1989_Zanardo,
author = {Andrea Zanardo and Rino A. Michelin and Francesco Pinna and Giorgio Strukul},
title = {Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity},
journal = {Inorganic Chemistry},
year = {1989},
volume = {28},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/ic00308a010},
number = {9},
pages = {1648--1653},
doi = {10.1021/ic00308a010}
}
MLA
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MLA Copy
Zanardo, Andrea, et al. “Epoxidation of olefins catalyzed by chelating diphosphine-platinum(II) complexes. Ring-size and ring-shape effects on the catalytic activity.” Inorganic Chemistry, vol. 28, no. 9, May. 1989, pp. 1648-1653. https://doi.org/10.1021/ic00308a010.