Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles
Тип публикации: Journal Article
Дата публикации: 1990-07-01
scimago Q1
wos Q1
БС1
SJR: 0.928
CiteScore: 7.6
Impact factor: 4.7
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The use of fluoro substituents has been tested as a means to stabilize the amide bond to divalent platinum. Products have been obtained which show that complexed fluoroalkyls and fluoroaryls have a high reactivity to nucleophiles. The complex trans-PtCF 3 Cl(PPh 3 ) 2 reacts with LiN(CH 3 ) 2 to give products derived from Pt(PPh 3 ) 2 . The complex trans-[PtCH 3 )THF)-(PPh 2 C 6 F 5 ) 2 ]ClO 4 , prepared from trans-PtCH 3 Cl(PPh 2 C 6 F 5 ) 2 and AgClO 4 in THF solvent, reacts with hydroxide ion to give the cyclometalated complex trans-PtCH 3 (2-OC 6 F 4 PPh 2 )(PPh 2 C 6 F 5 ). The crystal structure has a monoclinic P2 1 /c
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Park S., Pontier-Johnson M., Roundhill D. M. Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles // Inorganic Chemistry. 1990. Vol. 29. No. 14. pp. 2689-2697.
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Park S., Pontier-Johnson M., Roundhill D. M. Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles // Inorganic Chemistry. 1990. Vol. 29. No. 14. pp. 2689-2697.
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TY - JOUR
DO - 10.1021/ic00339a028
UR - https://doi.org/10.1021/ic00339a028
TI - Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles
T2 - Inorganic Chemistry
AU - Park, Soonheum
AU - Pontier-Johnson, Marie
AU - Roundhill, D. Max
PY - 1990
DA - 1990/07/01
PB - American Chemical Society (ACS)
SP - 2689-2697
IS - 14
VL - 29
SN - 0020-1669
SN - 1520-510X
ER -
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@article{1990_Park,
author = {Soonheum Park and Marie Pontier-Johnson and D. Max Roundhill},
title = {Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles},
journal = {Inorganic Chemistry},
year = {1990},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/ic00339a028},
number = {14},
pages = {2689--2697},
doi = {10.1021/ic00339a028}
}
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Park, Soonheum, et al. “Regioselective carbon-fluorine bond cleavage reactions from the interaction of transition metal fluorocarbon complexes with nucleophiles.” Inorganic Chemistry, vol. 29, no. 14, Jul. 1990, pp. 2689-2697. https://doi.org/10.1021/ic00339a028.