том 46 издание 9 страницы 3619-3622

Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride−Silicate:  K5Eu2FSi4O13

Тип публикацииJournal Article
Дата публикации2007-03-24
scimago Q1
wos Q1
БС1
SJR0.928
CiteScore7.6
Impact factor4.7
ISSN00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
The crystal structure and luminescence properties of flux-grown crystals of a new europium(III) fluoride-silicate, K5Eu2FSi4O13, are reported. The structure consists of octahedral dimers of the composition [Eu2O10F], which are linked by unbranched tetrasilicate chains to form a 3-D framework with 5- and 6-ring channels parallel to the b axis where the K+ cations are located. The sharp peaks in the room-temperature emission spectrum are assigned. The number of lines in the region for the 5D0-->7F0 transition and the relative intensities of the 5D0-->7F1 and 5D0-->7F2 transitions confirm the presence of two local Eu3+ environments and strongly distorted Eu3+-ligand surroundings. The room-temperature fluorescence decay curves are well fit by a single-exponential function yielding a lifetime value of about 2.0 ms. Crystal data: monoclinic, space group P21/m, a=7.1850(2) A, b=5.7981(2) A, c=18.1675(6) A, beta=92.248(2) degrees , and Z=2.
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ГОСТ |
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Chiang P. Y. et al. Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride−Silicate: K5Eu2FSi4O13 // Inorganic Chemistry. 2007. Vol. 46. No. 9. pp. 3619-3622.
ГОСТ со всеми авторами (до 50) Скопировать
Chiang P. Y., Lin T., Dai J. H., Chang B. C., Lii K. Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride−Silicate: K5Eu2FSi4O13 // Inorganic Chemistry. 2007. Vol. 46. No. 9. pp. 3619-3622.
RIS |
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TY - JOUR
DO - 10.1021/ic0700304
UR - https://doi.org/10.1021/ic0700304
TI - Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride−Silicate: K5Eu2FSi4O13
T2 - Inorganic Chemistry
AU - Chiang, Pei Yun
AU - Lin, Tsai-Wei
AU - Dai, Jian Hung
AU - Chang, Bor Chen
AU - Lii, Kwang-Hwa
PY - 2007
DA - 2007/03/24
PB - American Chemical Society (ACS)
SP - 3619-3622
IS - 9
VL - 46
PMID - 17381085
SN - 0020-1669
SN - 1520-510X
ER -
BibTex |
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@article{2007_Chiang,
author = {Pei Yun Chiang and Tsai-Wei Lin and Jian Hung Dai and Bor Chen Chang and Kwang-Hwa Lii},
title = {Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride−Silicate: K5Eu2FSi4O13},
journal = {Inorganic Chemistry},
year = {2007},
volume = {46},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ic0700304},
number = {9},
pages = {3619--3622},
doi = {10.1021/ic0700304}
}
MLA
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Chiang, Pei Yun, et al. “Flux Synthesis, Crystal Structure, and Luminescence Properties of a New Europium Fluoride−Silicate: K5Eu2FSi4O13.” Inorganic Chemistry, vol. 46, no. 9, Mar. 2007, pp. 3619-3622. https://doi.org/10.1021/ic0700304.