Macrocyclic complexes of palladium(II) with benzothiacrown ethers: Synthesis, characterization, and structure of cis and trans isomers
Тип публикации: Journal Article
Дата публикации: 2011-07-19
scimago Q1
wos Q1
БС1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
21766887
Inorganic Chemistry
Physical and Theoretical Chemistry
Краткое описание
A series of palladium(II) complexes with nitro- and formylbenzothiacrown-ether derivatives was synthesized. The spatial structure of the complexes was studied by NMR, X-ray diffraction analysis, and quantum chemical calculations (density functional theory). The cavity size and the ligand denticity were found to be crucial factors determining the geometric configuration of the thiacrown-ether complexes. Palladium(II) complexes with benzodithia-12(18)-crown-4(6) ethers were demonstrated to have a cis-configured S(2)PdY(2) fragment (Y = Cl, OAc). In the case of Pd(II) and benzodithia-21-crown-7 ethers, only complexes with a trans configuration of the S(2)PdY(2) fragment form. In the case of Pd(II) and nitrobenzomonothia-15-crown-5 ether, only 2(ligand):1(Pd) complex with trans configuration of the core fragment forms.
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Dmitrieva S. N. et al. Macrocyclic complexes of palladium(II) with benzothiacrown ethers: Synthesis, characterization, and structure of cis and trans isomers // Inorganic Chemistry. 2011. Vol. 50. No. 16. pp. 7500-7510.
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Dmitrieva S. N., Sidorenko N. I., Kurchavov N. A., Vedernikov A. I., Freidzon A. Y., Kuz'mina L. G., Buryak A. K., Buryak A. K., Buslaeva T. M., Bagatur'yants A. A., Bagaturyants A. A., Strelenko Y. A., Howard J. A., Howard J. A. K., Fomina M. V., Gromov S. P. Macrocyclic complexes of palladium(II) with benzothiacrown ethers: Synthesis, characterization, and structure of cis and trans isomers // Inorganic Chemistry. 2011. Vol. 50. No. 16. pp. 7500-7510.
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TY - JOUR
DO - 10.1021/ic2003063
UR - https://pubs.acs.org/doi/10.1021/ic2003063
TI - Macrocyclic complexes of palladium(II) with benzothiacrown ethers: Synthesis, characterization, and structure of cis and trans isomers
T2 - Inorganic Chemistry
AU - Dmitrieva, Svetlana N
AU - Sidorenko, Natalia I
AU - Kurchavov, Nikolay A
AU - Vedernikov, Artem I.
AU - Freidzon, Alexandra Ya.
AU - Kuz'mina, Lyudmila G.
AU - Buryak, Alexey Konstantinovich
AU - Buryak, Aleksei K
AU - Buslaeva, Tatyana M
AU - Bagatur'yants, A. A.
AU - Bagaturyants, Alexander A
AU - Strelenko, Yuri A.
AU - Howard, Judith A.
AU - Howard, Judith A. K.
AU - Fomina, Marina V.
AU - Gromov, Sergey P
PY - 2011
DA - 2011/07/19
PB - American Chemical Society (ACS)
SP - 7500-7510
IS - 16
VL - 50
PMID - 21766887
SN - 0020-1669
SN - 1520-510X
ER -
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@article{2011_Dmitrieva,
author = {Svetlana N Dmitrieva and Natalia I Sidorenko and Nikolay A Kurchavov and Artem I. Vedernikov and Alexandra Ya. Freidzon and Lyudmila G. Kuz'mina and Alexey Konstantinovich Buryak and Aleksei K Buryak and Tatyana M Buslaeva and A. A. Bagatur'yants and Alexander A Bagaturyants and Yuri A. Strelenko and Judith A. Howard and Judith A. K. Howard and Marina V. Fomina and Sergey P Gromov},
title = {Macrocyclic complexes of palladium(II) with benzothiacrown ethers: Synthesis, characterization, and structure of cis and trans isomers},
journal = {Inorganic Chemistry},
year = {2011},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://pubs.acs.org/doi/10.1021/ic2003063},
number = {16},
pages = {7500--7510},
doi = {10.1021/ic2003063}
}
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Dmitrieva, Svetlana N., et al. “Macrocyclic complexes of palladium(II) with benzothiacrown ethers: Synthesis, characterization, and structure of cis and trans isomers.” Inorganic Chemistry, vol. 50, no. 16, Jul. 2011, pp. 7500-7510. https://pubs.acs.org/doi/10.1021/ic2003063.
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