Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12
Publication type: Journal Article
Publication date: 2012-02-15
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
22335610
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
A mixture of higher fullerenes C(76)-C(96) was pentafluoroethylated with C(2)F(5)I at 250 °C affording a mixture of C(2)F(5) derivatives. After separation with high-performance liquid chromatography, the second C(2)F(5) derivative of C(84)(16), C(84)(C(2)F(5))(12), was investigated by X-ray crystallography and compared with the known isomer in terms of addition patterns and formation energies. Chlorination of a C(84) isomeric mixture with VCl(4) at 350-400 °C resulted in the formation of C(84)Cl(22). X-ray diffraction study revealed the superposition of several C(84)Cl(22) molecules with different isomeric C(84) cages but the same chlorination pattern.
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Lanskikh M. A. et al. Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12 // Inorganic Chemistry. 2012. Vol. 51. No. 5. pp. 2719-2721.
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Lanskikh M. A., Tamm N. B., Sidorov L. N., Troyanov S. Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12 // Inorganic Chemistry. 2012. Vol. 51. No. 5. pp. 2719-2721.
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TY - JOUR
DO - 10.1021/ic202210s
UR - https://doi.org/10.1021/ic202210s
TI - Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12
T2 - Inorganic Chemistry
AU - Lanskikh, Maria A
AU - Tamm, Nadezhda B
AU - Sidorov, Lev N.
AU - Troyanov, Sergey
PY - 2012
DA - 2012/02/15
PB - American Chemical Society (ACS)
SP - 2719-2721
IS - 5
VL - 51
PMID - 22335610
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2012_Lanskikh,
author = {Maria A Lanskikh and Nadezhda B Tamm and Lev N. Sidorov and Sergey Troyanov},
title = {Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12},
journal = {Inorganic Chemistry},
year = {2012},
volume = {51},
publisher = {American Chemical Society (ACS)},
month = {feb},
url = {https://doi.org/10.1021/ic202210s},
number = {5},
pages = {2719--2721},
doi = {10.1021/ic202210s}
}
Cite this
MLA
Copy
Lanskikh, Maria A., et al. “Capturing C84 Isomers as Chlorides and Pentafluoroethyl Derivatives: C84Cl22 and C84(C2F5)12.” Inorganic Chemistry, vol. 51, no. 5, Feb. 2012, pp. 2719-2721. https://doi.org/10.1021/ic202210s.