Inorganic Chemistry

, volume 52 , issue 4 , pages 2208-2218

Homologous series of layered perovskites An +1B nO3 n -1Cl: Crystal and magnetic structure of a new oxychloride Pb4BiFe4O11Cl

M. Batuk ¹

Maria Batuk ²

Dmitry Batuk ¹

A. A. Tsirlin ^{3, 4}

Alexander A. Tsirlin ^{3, 4}

Marina G Rozova ^{5, 6}

Evgeny V. Antipov ⁵

Joke Hadermann ¹

Gustaaf Van Tendeloo ^{1, 2}

Hide authors affiliations Show authors affiliations: 6 affiliations

Electron Microscopy for Materials Research (EMAT), University of Antwerp, Groenenborgerlaan 171, B-2020 Antwerp, Belgium |

National Institute of Chemical Physics and Biophysics, 12618 Tallinn, Estonia |

⁴

Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Strasse 40, 01187 Dresden, Germany |

⁵

Department of Chemistry, Moscow State University, 119992 Moscow, Russia |

⁶

Department of Chemistry, Moscow State University, 119992 Moscow, Russia |

Publication type: Journal Article

Publication date: 2013-02-05

American Chemical Society (ACS)

Inorganic Chemistry

scimago Q1

wos Q1

SJR: 0.958

CiteScore: 7.4

Impact factor: 4.7

ISSN: 00201669, 1520510X

DOI: 10.1021/ic302667a

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PubMed ID: 23379299

Inorganic Chemistry

Physical and Theoretical Chemistry

Abstract

The nuclear and magnetic structure of a novel oxychloride Pb(4)BiFe(4)O(11)Cl has been studied over the temperature range 1.5-700 K using a combination of transmission electron microscopy and synchrotron and neutron powder diffraction [space group P4/mbm, a = 5.5311(1) Å, c = 19.586(1) Å, T = 300 K]. Pb(4)BiFe(4)O(11)Cl is built of truncated (Pb,Bi)(3)Fe(4)O(11) quadruple perovskite blocks separated by CsCl-type (Pb,Bi)(2)Cl slabs. The perovskite blocks consist of two layers of FeO(6) octahedra located between two layers of FeO(5) tetragonal pyramids. The FeO(6) octahedra rotate about the c axis, resulting in a √2a(p) × √2a(p) × c superstructure. Below T(N) = 595(17) K, Pb(4)BiFe(4)O(11)Cl adopts a G-type antiferromagnetic structure with the iron magnetic moments confined to the ab plane. The ordered magnetic moments at 1.5 K are 3.93(3) and 3.62(4) μ(B) on the octahedral and square-pyramidal iron sites, respectively. Pb(4)BiFe(4)O(11)Cl can be considered a member of the perovskite-based A(n+1)B(n)O(3n-1)Cl homologous series (A = Pb/Bi; B = Fe) with n = 4. The formation of a subsequent member of the series with n = 5 is also demonstrated.

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Batuk M. et al. Homologous series of layered perovskites An +1B nO3 n -1Cl: Crystal and magnetic structure of a new oxychloride Pb4BiFe4O11Cl // Inorganic Chemistry. 2013. Vol. 52. No. 4. pp. 2208-2218.

GOST all authors (up to 50) Copy

Batuk M., Batuk M., Batuk D., Tsirlin A. A., Tsirlin A. A., Rozova M. G., Antipov E. V., Hadermann J., Van Tendeloo G. Homologous series of layered perovskites An +1B nO3 n -1Cl: Crystal and magnetic structure of a new oxychloride Pb4BiFe4O11Cl // Inorganic Chemistry. 2013. Vol. 52. No. 4. pp. 2208-2218.

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RIS Copy

TY - JOUR

DO - 10.1021/ic302667a

UR - https://pubs.acs.org/doi/10.1021/ic302667a

TI - Homologous series of layered perovskites An +1B nO3 n -1Cl: Crystal and magnetic structure of a new oxychloride Pb4BiFe4O11Cl

T2 - Inorganic Chemistry

AU - Batuk, M.

AU - Batuk, Maria

AU - Batuk, Dmitry

AU - Tsirlin, A. A.

AU - Tsirlin, Alexander A.

AU - Rozova, Marina G

AU - Antipov, Evgeny V.

AU - Hadermann, Joke

AU - Van Tendeloo, Gustaaf

PY - 2013

DA - 2013/02/05

PB - American Chemical Society (ACS)

SP - 2208-2218

IS - 4

VL - 52

PMID - 23379299

SN - 0020-1669

SN - 1520-510X

ER -

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@article{2013_Batuk,

author = {M. Batuk and Maria Batuk and Dmitry Batuk and A. A. Tsirlin and Alexander A. Tsirlin and Marina G Rozova and Evgeny V. Antipov and Joke Hadermann and Gustaaf Van Tendeloo},

title = {Homologous series of layered perovskites An +1B nO3 n -1Cl: Crystal and magnetic structure of a new oxychloride Pb4BiFe4O11Cl},

journal = {Inorganic Chemistry},

year = {2013},

volume = {52},

publisher = {American Chemical Society (ACS)},

month = {feb},

url = {https://pubs.acs.org/doi/10.1021/ic302667a},

number = {4},

pages = {2208--2218},

doi = {10.1021/ic302667a}

}

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Batuk, M., et al. “Homologous series of layered perovskites An +1B nO3 n -1Cl: Crystal and magnetic structure of a new oxychloride Pb4BiFe4O11Cl.” Inorganic Chemistry, vol. 52, no. 4, Feb. 2013, pp. 2208-2218. https://pubs.acs.org/doi/10.1021/ic302667a.