Inorganic Chemistry, volume 46, issue 14, pages 5805-5812
Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation
Publication type: Journal Article
Publication date: 2007-06-15
Journal:
Inorganic Chemistry
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 4.6
ISSN: 00201669, 1520510X
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Half-sandwich Ru(II) amine, thiol, and thiolate complexes were prepared and characterized by X-ray crystallography. The thiol and amine complexes react slowly with acetonitrile to give free thiol or amine and the acetonitrile complex. With the thiol complex, the reaction is dissociative. The thiolate complex has been oxidized to its Ru(III) radical cation and the solution EPR spectrum of that radical cation recorded. Cobaltocene reduces the thiol complex to the thiolate complex. The 1H and 31P NMR signals of the thiolate complex in acetonitrile become very broad whenever the thiolate and thiol complexes are present simultaneously. The line broadening is primarily due to electron exchange between the thiolate complex and its radical cation; the latter is generated by an unfavorable redox equilibrium between the thiol and thiolate complexes. Pyramidal inversion of sulfur in the thiol complex is fast at room temperature but slow at lower temperatures; major and minor conformers of the thiol complex were observed by 31P NMR at -98 degrees C in CD2Cl2.
Top-30
Citations by journals
|
1
2
3
4
|
|
|
Organometallics
4 publications, 17.39%
|
|
|
Dalton Transactions
3 publications, 13.04%
|
|
|
Journal of Organometallic Chemistry
2 publications, 8.7%
|
|
|
Polyhedron
2 publications, 8.7%
|
|
|
Australian Journal of Chemistry
1 publication, 4.35%
|
|
|
Inorganic Chemistry Communication
1 publication, 4.35%
|
|
|
European Journal of Inorganic Chemistry
1 publication, 4.35%
|
|
|
Inorganica Chimica Acta
1 publication, 4.35%
|
|
|
Zeitschrift fur Anorganische und Allgemeine Chemie
1 publication, 4.35%
|
|
|
Inorganic Chemistry
1 publication, 4.35%
|
|
|
ACS Catalysis
1 publication, 4.35%
|
|
|
Journal of Medicinal Chemistry
1 publication, 4.35%
|
|
|
Annual Reports Section A (Inorganic Chemistry)
1 publication, 4.35%
|
|
|
New Journal of Chemistry
1 publication, 4.35%
|
|
|
Applied Organometallic Chemistry
1 publication, 4.35%
|
|
|
Russian Chemical Reviews
1 publication, 4.35%
|
|
|
1
2
3
4
|
Citations by publishers
|
1
2
3
4
5
6
7
|
|
|
American Chemical Society (ACS)
7 publications, 30.43%
|
|
|
Elsevier
6 publications, 26.09%
|
|
|
Royal Society of Chemistry (RSC)
5 publications, 21.74%
|
|
|
Wiley
3 publications, 13.04%
|
|
|
CSIRO Publishing
1 publication, 4.35%
|
|
|
Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii
1 publication, 4.35%
|
|
|
1
2
3
4
5
6
7
|
- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
{"yearsCitations":{"type":"bar","data":{"show":true,"labels":[2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["","","","","","","","","","","","","","","","",""],"datasets":[{"label":"Citations number","data":[2,0,2,1,2,1,0,4,2,3,0,0,0,1,2,1,2],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":["8.7",0,"8.7","4.35","8.7","4.35",0,"17.39","8.7","13.04",0,0,0,"4.35","8.7","4.35","8.7"],"barThickness":null}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"journals":{"type":"bar","data":{"show":true,"labels":["Organometallics","Dalton Transactions","Journal of Organometallic Chemistry","Polyhedron","Australian Journal of Chemistry","Inorganic Chemistry Communication","European Journal of Inorganic Chemistry","Inorganica Chimica Acta","Zeitschrift fur Anorganische und Allgemeine Chemie","Inorganic Chemistry","ACS Catalysis","Journal of Medicinal Chemistry","Annual Reports Section A (Inorganic Chemistry)","New Journal of Chemistry","Applied Organometallic Chemistry","Russian Chemical Reviews"],"ids":[1409,8473,11834,21269,169,22802,15359,1406,18677,24714,4873,3673,25861,1404,11683,23802],"codes":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/se1SPF1aqPN9oZ2Pvhp519I0unlLQM7LOKSeYPe8_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[4,3,2,2,1,1,1,1,1,1,1,1,1,1,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[17.39,13.04,8.7,8.7,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35,4.35],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Journals","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"publishers":{"type":"bar","data":{"show":true,"labels":["American Chemical Society (ACS)","Elsevier","Royal Society of Chemistry (RSC)","Wiley","CSIRO Publishing","Autonomous Non-profit Organization Editorial Board of the journal Uspekhi Khimii"],"ids":[40,17,123,11,7016,9422],"codes":[0,0,0,0,0,0],"imageUrls":["\/storage\/images\/resized\/iLiQsFqFaSEx6chlGQ5fbAwF6VYU3WWa08hkss0g_medium.webp","\/storage\/images\/resized\/GDnYOu1UpMMfMMRV6Aqle4H0YLLsraeD9IP9qScG_medium.webp","\/storage\/images\/resized\/leiAYcRDGTSl5B1eCnwpSGqmDEUEfDPPoYisFGhT_medium.webp","\/storage\/images\/resized\/bRyGpdm98BkAUYiK1YFNpl5Z7hPu6Gd87gbIeuG3_medium.webp","\/storage\/images\/resized\/se1SPF1aqPN9oZ2Pvhp519I0unlLQM7LOKSeYPe8_medium.webp","\/storage\/images\/resized\/9Mus3KG1Tkd7Bwaurt8H3RwWh0CxRlGoO6ng9UK1_medium.webp"],"datasets":[{"label":"","data":[7,6,5,3,1,1],"backgroundColor":["#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6","#3B82F6"],"percentage":[30.43,26.09,21.74,13.04,4.35,4.35],"barThickness":13}]},"options":{"indexAxis":"y","maintainAspectRatio":false,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false},"x":{"ticks":{"stepSize":null,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":false}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Publishers","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartiles":{"type":"bar","data":{"show":true,"labels":[2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[1,0,0,0,0,1,0,1,0,1,0,0,0,0,0,0,0],"percentage":["4.35","0","0","0","0","4.35","0","4.35","0","4.35","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[0,0,1,0,1,0,0,1,1,1,0,0,0,0,0,1,1],"percentage":["0","0","4.35","0","4.35","0","0","4.35","4.35","4.35","0","0","0","0","0","4.35","4.35"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,0,1,1,1,0,0,2,1,1,0,0,0,1,2,0,1],"percentage":["0","0","4.35","4.35","4.35","0","0","8.7","4.35","4.35","0","0","0","4.35","8.7","0","4.35"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"percentage":["4.35","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by SCImago per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}},"yearsCitationsQuartilesWs":{"type":"bar","data":{"show":true,"labels":[2008,2009,2010,2011,2012,2013,2014,2015,2016,2017,2018,2019,2020,2021,2022,2023,2024],"ids":[],"codes":[],"imageUrls":[],"datasets":[{"label":"Q4","backgroundColor":"rgb(221,90,78)","data":[0,0,0,0,0,1,0,0,0,1,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","4.35","0","0","0","4.35","0","0","0","0","0","0","0"]},{"label":"Q3","backgroundColor":"rgb(251, 163,83)","data":[0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"percentage":["0","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0"]},{"label":"Q2","backgroundColor":"rgb(232, 213, 89)","data":[1,0,1,0,1,0,0,4,1,1,0,0,0,0,1,1,0],"percentage":["4.35","0","4.35","0","4.35","0","0","17.39","4.35","4.35","0","0","0","0","4.35","4.35","0"]},{"label":"Q1","backgroundColor":"rgb(164, 207, 99)","data":[0,0,1,1,1,0,0,0,1,1,0,0,0,1,1,0,2],"percentage":["0","0","4.35","4.35","4.35","0","0","0","4.35","4.35","0","0","0","4.35","4.35","0","8.7"]},{"label":"Quartile not defined","backgroundColor":"#E5E7EB","data":[1,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0,0],"percentage":["4.35","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0","0"]}]},"options":{"indexAxis":"x","maintainAspectRatio":true,"scales":{"y":{"ticks":{"precision":0,"autoSkip":false,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true},"x":{"ticks":{"stepSize":1,"precision":0,"font":{"family":"Montserrat"},"color":"#000000"},"stacked":true}},"plugins":{"legend":{"position":"top","labels":{"font":{"family":"Montserrat"},"color":"#000000"}},"title":{"display":true,"text":"Citations quartiles by WoS per year","font":{"size":24,"family":"Montserrat","weight":600},"color":"#000000"}}}}}
Are you a researcher?
Create a profile to get free access to personal recommendations for colleagues and new articles.
Metrics
Cite this
GOST |
RIS |
BibTex |
MLA
Cite this
GOST
Copy
Shaw A. P. et al. Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation // Inorganic Chemistry. 2007. Vol. 46. No. 14. pp. 5805-5812.
GOST all authors (up to 50)
Copy
Shaw A. P., Ryland B. L., Norton J. R., Buccella D., Moscatelli A. Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation // Inorganic Chemistry. 2007. Vol. 46. No. 14. pp. 5805-5812.
Cite this
RIS
Copy
TY - JOUR
DO - 10.1021/ic700580u
UR - https://doi.org/10.1021/ic700580u
TI - Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation
T2 - Inorganic Chemistry
AU - Shaw, Anthony P
AU - Ryland, Bradford L
AU - Moscatelli, Alberto
AU - Norton, Jack R
AU - Buccella, Daniela
PY - 2007
DA - 2007/06/15 00:00:00
PB - American Chemical Society (ACS)
SP - 5805-5812
IS - 14
VL - 46
SN - 0020-1669
SN - 1520-510X
ER -
Cite this
BibTex
Copy
@article{2007_Shaw,
author = {Anthony P Shaw and Bradford L Ryland and Alberto Moscatelli and Jack R Norton and Daniela Buccella},
title = {Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation},
journal = {Inorganic Chemistry},
year = {2007},
volume = {46},
publisher = {American Chemical Society (ACS)},
month = {jun},
url = {https://doi.org/10.1021/ic700580u},
number = {14},
pages = {5805--5812},
doi = {10.1021/ic700580u}
}
Cite this
MLA
Copy
Shaw, Anthony P., et al. “Electron Exchange Involving a Sulfur-Stabilized Ruthenium Radical Cation.” Inorganic Chemistry, vol. 46, no. 14, Jun. 2007, pp. 5805-5812. https://doi.org/10.1021/ic700580u.