Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox
Publication type: Journal Article
Publication date: 2008-03-01
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
18311916
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
Solution calorimetry, using 6.0 M HCl as a solvent, is used to study the thermochemistry of Gd2BaCuO5 and the high-temperature superconductor LuBa2Cu3O6.92. For the first time, the standard formation enthalpies of these phases have been determined as follows: DeltafH(o)(Gd2BaCuO 5, s, 298.15 K) = -2618.6 +/- 7.4 kJ/mol; DeltafH(o)(LuBa2Cu3O6.92, s, 298.15 K) = -2693.1 +/- 11.9 kJ/mol. The thermodynamic stability at room temperature has been assessed. The results show that Gd211 and Lu123 are thermodynamically stable with respect to binary oxides and unstable with respect to interaction with CO 2 at ambient temperatures. Lu123 is thermodynamically stable with respect to assemblages containing combinations of Lu2O3, CuO, and BaCuO2 and thermodynamically unstable with respect to interactions with water.
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Matskevich N., WOLF T., Pochivalov Y. I. Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox // Inorganic Chemistry. 2008. Vol. 47. No. 7. pp. 2581-2584.
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Matskevich N., WOLF T., Pochivalov Y. I. Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox // Inorganic Chemistry. 2008. Vol. 47. No. 7. pp. 2581-2584.
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TY - JOUR
DO - 10.1021/ic701875h
UR - https://doi.org/10.1021/ic701875h
TI - Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox
T2 - Inorganic Chemistry
AU - Matskevich, N.I.
AU - WOLF, THOMAS
AU - Pochivalov, Yurii I
PY - 2008
DA - 2008/03/01
PB - American Chemical Society (ACS)
SP - 2581-2584
IS - 7
VL - 47
PMID - 18311916
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2008_Matskevich,
author = {N.I. Matskevich and THOMAS WOLF and Yurii I Pochivalov},
title = {Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox},
journal = {Inorganic Chemistry},
year = {2008},
volume = {47},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ic701875h},
number = {7},
pages = {2581--2584},
doi = {10.1021/ic701875h}
}
Cite this
MLA
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Matskevich, N.I., et al. “Thermochemistry of Gd2BaCuO5 and LuBa2Cu3Ox.” Inorganic Chemistry, vol. 47, no. 7, Mar. 2008, pp. 2581-2584. https://doi.org/10.1021/ic701875h.