Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes
Publication type: Journal Article
Publication date: 2009-09-07
scimago Q1
wos Q1
SJR: 0.958
CiteScore: 7.4
Impact factor: 4.7
ISSN: 00201669, 1520510X
PubMed ID:
19678668
Inorganic Chemistry
Physical and Theoretical Chemistry
Abstract
New binary ligands consisting of 2,2':6',2''-terpyridine and 2,2'-bipyridine were synthesized through the linkage of various lengths of the polymethylene chain (1a-1d; n = 3-6, where n is the number of CH(2) units). Their Co(II) complexes, 2a-2d (Cl complexes) and 2a'-2d' (H(2)O complexes), were synthesized. They exclusively formed mononuclear complexes, which could be oxidized to Co(III) complexes in aqueous solutions after prolonged exposure to the air. The single crystals of 2b and Co(III) complex 2c'' were obtained, and their crystal structures were determined. Cyclic voltammograms of the Co(II) complexes showed the redox processes of the terpyridine, Co(II)/Co(I), and Co(III)/Co(II). The redox waves of Co(II)/Co(I) in 2a and 2a' were slightly different from those of other complexes because of the short polymethylene chain.
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Citations from 2025:
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Kon H. Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes // Inorganic Chemistry. 2009. Vol. 48. No. 17. pp. 8593-8602.
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Kon H. Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes // Inorganic Chemistry. 2009. Vol. 48. No. 17. pp. 8593-8602.
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RIS
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TY - JOUR
DO - 10.1021/ic900932j
UR - https://doi.org/10.1021/ic900932j
TI - Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes
T2 - Inorganic Chemistry
AU - Kon, Hiroki
PY - 2009
DA - 2009/09/07
PB - American Chemical Society (ACS)
SP - 8593-8602
IS - 17
VL - 48
PMID - 19678668
SN - 0020-1669
SN - 1520-510X
ER -
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BibTex (up to 50 authors)
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@article{2009_Kon,
author = {Hiroki Kon},
title = {Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes},
journal = {Inorganic Chemistry},
year = {2009},
volume = {48},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ic900932j},
number = {17},
pages = {8593--8602},
doi = {10.1021/ic900932j}
}
Cite this
MLA
Copy
Kon, Hiroki. “Syntheses of the Terpyridine−Bipyridine Linked Binary Ligands and Structural and Redox Properties of Their Cobalt Complexes.” Inorganic Chemistry, vol. 48, no. 17, Sep. 2009, pp. 8593-8602. https://doi.org/10.1021/ic900932j.