Prediction of high-pressure vapor-liquid equilibria using the Soave-Redlich-Kwong group contribution method
Publication type: Journal Article
Publication date: 1990-10-01
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
High-pressure vapor-liquid equilibria (VLE) are predicted by applying ASOG-type and UNIFAC-type group contribution methods to the residual excess free energy g E(R) ∞ in the mixing rule a=ΣΣx i x j (a ii a jj ) 0.5 -(b/ln 2)g E(R) ∞, which is derived for the mixture energy parameter in the SRK equation of state. The group interaction parameters are determined for 14 groups, i.e., CH 2 , OH, KCO(CH 2 CO), CH 3 OH, H 2 O, CH 4 , C 2 H 6 , C 3 H 8 , C 4 H 10 , H 2 , N 2 , CO 2 , CO, and H 2 S, using binary VLE data in the temperature range 70-660K. The VLE are then predicted for 90 binary and 19 ternary systems made up of alcohols, water, ketones, n-paraffins, hydrogen, nitrogen, carbon dioxide, carbon monoxide, and hydrogen sulfide
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Tochigi K., Kurihara K., Kojima K. Prediction of high-pressure vapor-liquid equilibria using the Soave-Redlich-Kwong group contribution method // Industrial & Engineering Chemistry Research. 1990. Vol. 29. No. 10. pp. 2142-2149.
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Tochigi K., Kurihara K., Kojima K. Prediction of high-pressure vapor-liquid equilibria using the Soave-Redlich-Kwong group contribution method // Industrial & Engineering Chemistry Research. 1990. Vol. 29. No. 10. pp. 2142-2149.
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TY - JOUR
DO - 10.1021/ie00106a027
UR - https://doi.org/10.1021/ie00106a027
TI - Prediction of high-pressure vapor-liquid equilibria using the Soave-Redlich-Kwong group contribution method
T2 - Industrial & Engineering Chemistry Research
AU - Tochigi, Katsumi
AU - Kurihara, Kiyofumi
AU - Kojima, Kazuo
PY - 1990
DA - 1990/10/01
PB - American Chemical Society (ACS)
SP - 2142-2149
IS - 10
VL - 29
SN - 0888-5885
SN - 1520-5045
ER -
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@article{1990_Tochigi,
author = {Katsumi Tochigi and Kiyofumi Kurihara and Kazuo Kojima},
title = {Prediction of high-pressure vapor-liquid equilibria using the Soave-Redlich-Kwong group contribution method},
journal = {Industrial & Engineering Chemistry Research},
year = {1990},
volume = {29},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/ie00106a027},
number = {10},
pages = {2142--2149},
doi = {10.1021/ie00106a027}
}
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Tochigi, Katsumi, et al. “Prediction of high-pressure vapor-liquid equilibria using the Soave-Redlich-Kwong group contribution method.” Industrial & Engineering Chemistry Research, vol. 29, no. 10, Oct. 1990, pp. 2142-2149. https://doi.org/10.1021/ie00106a027.