N2O Decomposition over Perovskite Catalysts
Publication type: Journal Article
Publication date: 2007-03-17
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
Four perovskite catalysts LaBO3 (where B = Cr, Mn, Fe, and Co) were prepared via a highly exothermic and self-sustaining reaction, the so-called “solution combustion synthesis (SCS)”, and characterized by means of X-ray diffraction, BET, field-emission scanning electron microscopy−energy-dispersive spectrometry, and H2-temperature-programmed reduction (TPR) analyses. The performance of these catalysts toward the decomposition of N2O to N2 and O2 was evaluated in a temperature programmed reaction (TPRe) apparatus in the absence and the presence of different oxygen concentrations. Among the catalysts screened, LaCoO3 showed the best performance, with 50% conversion of N2O at 455 °C and 490 °C in the absence and presence of 5% of oxygen, respectively. The LaCoO3 catalyst was deposited by in situ SCS directly over a ceramic honeycomb monolith and then tested in a lab-scale test rig. The coated ceramic monolith gave 50% N2O conversion performance similar to that obtained on powder for GHSV values of industrial...
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119
Total citations:
119
Citations from 2025:
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(4.2%)
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GOST
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RUSSO N. et al. N2O Decomposition over Perovskite Catalysts // Industrial & Engineering Chemistry Research. 2007. Vol. 46. No. 12. pp. 4226-4231.
GOST all authors (up to 50)
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RUSSO N., Mescia D., Fino D., Saracco G., Specchia V. N2O Decomposition over Perovskite Catalysts // Industrial & Engineering Chemistry Research. 2007. Vol. 46. No. 12. pp. 4226-4231.
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RIS
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TY - JOUR
DO - 10.1021/ie0612008
UR - https://doi.org/10.1021/ie0612008
TI - N2O Decomposition over Perovskite Catalysts
T2 - Industrial & Engineering Chemistry Research
AU - RUSSO, N.
AU - Mescia, D
AU - Fino, D
AU - Saracco, Guido
AU - Specchia, V.
PY - 2007
DA - 2007/03/17
PB - American Chemical Society (ACS)
SP - 4226-4231
IS - 12
VL - 46
SN - 0888-5885
SN - 1520-5045
ER -
Cite this
BibTex (up to 50 authors)
Copy
@article{2007_RUSSO,
author = {N. RUSSO and D Mescia and D Fino and Guido Saracco and V. Specchia},
title = {N2O Decomposition over Perovskite Catalysts},
journal = {Industrial & Engineering Chemistry Research},
year = {2007},
volume = {46},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/ie0612008},
number = {12},
pages = {4226--4231},
doi = {10.1021/ie0612008}
}
Cite this
MLA
Copy
RUSSO, N., et al. “N2O Decomposition over Perovskite Catalysts.” Industrial & Engineering Chemistry Research, vol. 46, no. 12, Mar. 2007, pp. 4226-4231. https://doi.org/10.1021/ie0612008.