Effect of the Functional Group on the Hydrodechlorination of Chlorinated Aromatic Compounds over Pd, Ru, and Rh Supported on Carbon
Тип публикации: Journal Article
Дата публикации: 2010-09-15
SCImago Q1
WOS Q2
БС1
SJR: 0.756
CiteScore: 6.6
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Краткое описание
The effect of a functional group on the hydrodechlorination chlorinated aromatic compounds on Pd/C, Ru/C, and Rh/C catalysts was studied in liquid phase at 30 °C and 2 kg/cm 2 of hydrogen pressure, using 200 ppm of the chlorinated organic compound. An effect of particle size on Pd catalysts was observed, small particles showed to be more resistant to the deposit of chloride from the reaction. The activity in the hydrodechlorination of organic compounds as a function of the functional group increases in the following order p-chlorophenol > p-chlorotoluene > p-dichlorobenzene. The activity in the hydrodechlorination of these molecules increases with the presence of donating groups as ―CH 3 and ―OH. The p-chlorotoluene hydrodechlorination on Ru and Rh leads also to the hydrogenation of the aromatic ring (toluene, methylcyclohexane). On the other hand, the p-chlorophenol hydrodechlorination over Pd, Ru, and Rh produces deoxygenated products (chlorobenzene, phenol, and benzene). Pd showed the highest activity followed by Ru and Rh.
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Benítez J. L., Angel G. D. Effect of the Functional Group on the Hydrodechlorination of Chlorinated Aromatic Compounds over Pd, Ru, and Rh Supported on Carbon // Industrial & Engineering Chemistry Research. 2010. Vol. 50. No. 5. pp. 2678-2682.
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Benítez J. L., Angel G. D. Effect of the Functional Group on the Hydrodechlorination of Chlorinated Aromatic Compounds over Pd, Ru, and Rh Supported on Carbon // Industrial & Engineering Chemistry Research. 2010. Vol. 50. No. 5. pp. 2678-2682.
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TY - JOUR
DO - 10.1021/ie100702s
UR - https://doi.org/10.1021/ie100702s
TI - Effect of the Functional Group on the Hydrodechlorination of Chlorinated Aromatic Compounds over Pd, Ru, and Rh Supported on Carbon
T2 - Industrial & Engineering Chemistry Research
AU - Benítez, José Luis
AU - Angel, Gloria Del
PY - 2010
DA - 2010/09/15
PB - American Chemical Society (ACS)
SP - 2678-2682
IS - 5
VL - 50
SN - 0888-5885
SN - 1520-5045
ER -
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@article{2010_Benítez,
author = {José Luis Benítez and Gloria Del Angel},
title = {Effect of the Functional Group on the Hydrodechlorination of Chlorinated Aromatic Compounds over Pd, Ru, and Rh Supported on Carbon},
journal = {Industrial & Engineering Chemistry Research},
year = {2010},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/ie100702s},
number = {5},
pages = {2678--2682},
doi = {10.1021/ie100702s}
}
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MLA
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Benítez, José Luis, and Gloria Del Angel. “Effect of the Functional Group on the Hydrodechlorination of Chlorinated Aromatic Compounds over Pd, Ru, and Rh Supported on Carbon.” Industrial & Engineering Chemistry Research, vol. 50, no. 5, Sep. 2010, pp. 2678-2682. https://doi.org/10.1021/ie100702s.
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