Copper and Nickel Modified MCM-41 An Efficient Catalyst for Hydrodehalogenation of Chlorobenzene at Room Temperature
Publication type: Journal Article
Publication date: 2011-01-24
scimago Q1
wos Q2
SJR: 0.828
CiteScore: 6.7
Impact factor: 3.9
ISSN: 08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
The paper reports preparation, surface, and textural characterization of Cu and Ni modified MCM-41 and its application for hydrodehalogenation of chlorobenzene. A series of Cu/Ni modified MCM-41 samples were synthesized by the co-condensation method by varying the amount of Ni and further characterized by various physicochemical methods. The incorporation of metals in the framework of mesoporous silica matrix was confirmed by X-ray diffraction (XRD) and Fourier transform infrared spectroscopy (FTIR). Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) studies showed the formation of uniform spherical particles on the support surface. The catalytic activity of the samples was evaluated toward the hydrodehalogenation reaction of chlorobenzene at room temperature. Samples containing Si/(Cu + Ni) = 10 showed the highest chlorobenzene (98%) conversion with 100% selectivity for benzene. Among the various solvents studied for the reaction, isopropyl alcohol gave the best results at 2 h ...
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76
Total citations:
76
Citations from 2024:
8
(10%)
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GOST
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Rath D., Parida K. Copper and Nickel Modified MCM-41 An Efficient Catalyst for Hydrodehalogenation of Chlorobenzene at Room Temperature // Industrial & Engineering Chemistry Research. 2011. Vol. 50. No. 5. pp. 2839-2849.
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Rath D., Parida K. Copper and Nickel Modified MCM-41 An Efficient Catalyst for Hydrodehalogenation of Chlorobenzene at Room Temperature // Industrial & Engineering Chemistry Research. 2011. Vol. 50. No. 5. pp. 2839-2849.
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RIS
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TY - JOUR
DO - 10.1021/ie101314f
UR - https://doi.org/10.1021/ie101314f
TI - Copper and Nickel Modified MCM-41 An Efficient Catalyst for Hydrodehalogenation of Chlorobenzene at Room Temperature
T2 - Industrial & Engineering Chemistry Research
AU - Rath, Dharitri
AU - Parida, K.M
PY - 2011
DA - 2011/01/24
PB - American Chemical Society (ACS)
SP - 2839-2849
IS - 5
VL - 50
SN - 0888-5885
SN - 1520-5045
ER -
Cite this
BibTex (up to 50 authors)
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@article{2011_Rath,
author = {Dharitri Rath and K.M Parida},
title = {Copper and Nickel Modified MCM-41 An Efficient Catalyst for Hydrodehalogenation of Chlorobenzene at Room Temperature},
journal = {Industrial & Engineering Chemistry Research},
year = {2011},
volume = {50},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ie101314f},
number = {5},
pages = {2839--2849},
doi = {10.1021/ie101314f}
}
Cite this
MLA
Copy
Rath, Dharitri, and K.M Parida. “Copper and Nickel Modified MCM-41 An Efficient Catalyst for Hydrodehalogenation of Chlorobenzene at Room Temperature.” Industrial & Engineering Chemistry Research, vol. 50, no. 5, Jan. 2011, pp. 2839-2849. https://doi.org/10.1021/ie101314f.