volume 36 issue 1 pages 179-186

Removal of Copper(II) Chelates of EDTA and NTA from Dilute Aqueous Solutions by Membrane Filtration

Ruey-Shin Juang 1
Ming Nan Chen 1
1
 
Department of Chemical Engineering, Yuan-Ze Institute of Technology, Nei-Li, Taoyuan, 320, Taiwan, ROC
Publication typeJournal Article
Publication date1997-01-01
scimago Q1
wos Q2
SJR0.828
CiteScore6.7
Impact factor3.9
ISSN08885885, 15205045
General Chemistry
General Chemical Engineering
Industrial and Manufacturing Engineering
Abstract
The removal of Cu(II) chelates of ethylenediaminetetraacetic acid (EDTA) and nitrilotriacetic acid (NTA) from aqueous solutions was studied by batch ultrafiltration (UF) with the help of poly(ethylenimine) (PEI). The Amicon regenerated cellulose YM10 and YM30 were used as ultrafilters. Experiments were performed as a function of aqueous pH, the concentration ratios of chelating agent to Cu(II) ions (α) and of PEI to Cu(II) ions (β), and the applied pressure (ΔP). In general, the removal of Cu−EDTA chelates was more effective compared to that of Cu−NTA chelates. Under the conditions tested (pH 4, ΔP = 2.04 atm, [Cu2+] 0.5 and β > 10 and higher than 96% for Cu−NTA chelates when α > 0.5 and β > 20. The effect of the presence of inorganic salts on the removal was also investigated. Finally, the membrane fouling during UF was analyzed by modified fouling index, and the regeneration of PEI was examined.
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GOST |
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GOST Copy
Juang R., Chen M. N. Removal of Copper(II) Chelates of EDTA and NTA from Dilute Aqueous Solutions by Membrane Filtration // Industrial & Engineering Chemistry Research. 1997. Vol. 36. No. 1. pp. 179-186.
GOST all authors (up to 50) Copy
Juang R., Chen M. N. Removal of Copper(II) Chelates of EDTA and NTA from Dilute Aqueous Solutions by Membrane Filtration // Industrial & Engineering Chemistry Research. 1997. Vol. 36. No. 1. pp. 179-186.
RIS |
Cite this
RIS Copy
TY - JOUR
DO - 10.1021/ie960311b
UR - https://doi.org/10.1021/ie960311b
TI - Removal of Copper(II) Chelates of EDTA and NTA from Dilute Aqueous Solutions by Membrane Filtration
T2 - Industrial & Engineering Chemistry Research
AU - Juang, Ruey-Shin
AU - Chen, Ming Nan
PY - 1997
DA - 1997/01/01
PB - American Chemical Society (ACS)
SP - 179-186
IS - 1
VL - 36
SN - 0888-5885
SN - 1520-5045
ER -
BibTex |
Cite this
BibTex (up to 50 authors) Copy
@article{1997_Juang,
author = {Ruey-Shin Juang and Ming Nan Chen},
title = {Removal of Copper(II) Chelates of EDTA and NTA from Dilute Aqueous Solutions by Membrane Filtration},
journal = {Industrial & Engineering Chemistry Research},
year = {1997},
volume = {36},
publisher = {American Chemical Society (ACS)},
month = {jan},
url = {https://doi.org/10.1021/ie960311b},
number = {1},
pages = {179--186},
doi = {10.1021/ie960311b}
}
MLA
Cite this
MLA Copy
Juang, Ruey-Shin, and Ming Nan Chen. “Removal of Copper(II) Chelates of EDTA and NTA from Dilute Aqueous Solutions by Membrane Filtration.” Industrial & Engineering Chemistry Research, vol. 36, no. 1, Jan. 1997, pp. 179-186. https://doi.org/10.1021/ie960311b.