The Journal of Physical Chemistry, volume 94, issue 10, pages 4356-4363
Dynamics of electron-hole pair recombination in semiconductor clusters
Publication type: Journal Article
Publication date: 1990-05-01
Journal:
The Journal of Physical Chemistry
SJR: —
CiteScore: —
Impact factor: —
ISSN: 00223654, 15415740
Physical and Theoretical Chemistry
General Engineering
Abstract
The kinetics of radiative electron-hole pair recombination in CdS and Cd{sub 3}As{sub 2} clusters (where the radius of the cluster is smaller than the de Broglie wavelength of photogenerated excitons) were studied with picosecond photon counting luminescence decay measurements over wide temperature and energy ranges. The decay profiles were quantitatively examined with several models. The decays are composed of two distinct time regimes, each with very different temperature and emission energy dependence. The first (fast) regime is attributed to an unusually efficient thermal repopulation mechanism. The second (slow) component is well described by a distributed kinetic model. The kinetic behavior of wide (CdS) and narrow (Cd{sub 3}As{sub 2}) band gap materials was remarkably similar when composed of clusters in the quantum confined regime.
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O'Neil M., Marohn J. A., Mclendon G. Dynamics of electron-hole pair recombination in semiconductor clusters // The Journal of Physical Chemistry. 1990. Vol. 94. No. 10. pp. 4356-4363.
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O'Neil M., Marohn J. A., Mclendon G. Dynamics of electron-hole pair recombination in semiconductor clusters // The Journal of Physical Chemistry. 1990. Vol. 94. No. 10. pp. 4356-4363.
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TY - JOUR
DO - 10.1021/j100373a089
UR - https://doi.org/10.1021/j100373a089
TI - Dynamics of electron-hole pair recombination in semiconductor clusters
T2 - The Journal of Physical Chemistry
AU - O'Neil, M
AU - Marohn, John A.
AU - Mclendon, G
PY - 1990
DA - 1990/05/01
PB - American Chemical Society (ACS)
SP - 4356-4363
IS - 10
VL - 94
SN - 0022-3654
SN - 1541-5740
ER -
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BibTex (up to 50 authors)
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@article{1990_O'Neil,
author = {M O'Neil and John A. Marohn and G Mclendon},
title = {Dynamics of electron-hole pair recombination in semiconductor clusters},
journal = {The Journal of Physical Chemistry},
year = {1990},
volume = {94},
publisher = {American Chemical Society (ACS)},
month = {may},
url = {https://doi.org/10.1021/j100373a089},
number = {10},
pages = {4356--4363},
doi = {10.1021/j100373a089}
}
Cite this
MLA
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O'Neil, M., et al. “Dynamics of electron-hole pair recombination in semiconductor clusters.” The Journal of Physical Chemistry, vol. 94, no. 10, May. 1990, pp. 4356-4363. https://doi.org/10.1021/j100373a089.