Reactions of hydroperoxo and superoxide with iodine and bromine and the iodide (I2-) and iodine atom reduction potentials
Тип публикации: Journal Article
Дата публикации: 1986-03-01
SJR: 1.641
CiteScore: —
Impact factor: —
ISSN: 00223654, 15415740
Physical and Theoretical Chemistry
General Engineering
Краткое описание
The equilibrium constant for reaction of HO/sub 2/ with I/sub 2/ to form H/sup +/, O/sub 2/, and I/sub 2//sup -/ was measured to be 30 M at 25 /sup 0/C. Derived free energies are ..delta..G/sub f//sup 0/(I/sub 2//sup -/) = -0.9 kcal/mol and ..delta..G/sub f//sup 0/(I/sub aq/) = 18.3 kcal/mol. Reduction potentials are E/sup 0/(I/sub 2(aq)//I/sub 2//sup -/) = 0.21 V, E/sup 0/(I/sub 2//sup -//2I/sup -/) = 1.03 V, and E/sup 0/(I/I/sup -/) = 1.33 V. Rate constants for reaction of HO/sub 2/ with I/sub 2/ and Br/sub 2/ are 1.8 x 10/sup 7/ and 1.3 x 10/sup 8/ M/sup -1/ s/sup -1/. Rate constants for O/sub 2//sup -/ reactions with I/sub 2/, I/sub 3//sup -/, Br/sub 2/, Br/sub 3//sup -/, and HOBr are 6.0 x 10/sup 9/, 0.25 x 10/sup 9/, 5 x 10/sup 9/, 1.5 x 10/sup 9/, and 3.5 x 10/sup 9/, and 3.5 x 10/sup 9/ M/sup -1/ s/sup -1/. The activation energies for reaction of O/sub 2//sup -/ with I/sub 2/ and with I/sub 3//sup -/ are 3.3 and 4.9 kcal/mol. 15 references, 4 figures, 1 table.
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Schwarz H. A., Bielski B. H. J. Reactions of hydroperoxo and superoxide with iodine and bromine and the iodide (I2-) and iodine atom reduction potentials // The Journal of Physical Chemistry. 1986. Vol. 90. No. 7. pp. 1445-1448.
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Schwarz H. A., Bielski B. H. J. Reactions of hydroperoxo and superoxide with iodine and bromine and the iodide (I2-) and iodine atom reduction potentials // The Journal of Physical Chemistry. 1986. Vol. 90. No. 7. pp. 1445-1448.
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TY - JOUR
DO - 10.1021/j100398a045
UR - https://doi.org/10.1021/j100398a045
TI - Reactions of hydroperoxo and superoxide with iodine and bromine and the iodide (I2-) and iodine atom reduction potentials
T2 - The Journal of Physical Chemistry
AU - Schwarz, Harold A.
AU - Bielski, Benon H J
PY - 1986
DA - 1986/03/01
PB - American Chemical Society (ACS)
SP - 1445-1448
IS - 7
VL - 90
SN - 0022-3654
SN - 1541-5740
ER -
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@article{1986_Schwarz,
author = {Harold A. Schwarz and Benon H J Bielski},
title = {Reactions of hydroperoxo and superoxide with iodine and bromine and the iodide (I2-) and iodine atom reduction potentials},
journal = {The Journal of Physical Chemistry},
year = {1986},
volume = {90},
publisher = {American Chemical Society (ACS)},
month = {mar},
url = {https://doi.org/10.1021/j100398a045},
number = {7},
pages = {1445--1448},
doi = {10.1021/j100398a045}
}
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MLA
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Schwarz, Harold A., and Benon H J Bielski. “Reactions of hydroperoxo and superoxide with iodine and bromine and the iodide (I2-) and iodine atom reduction potentials.” The Journal of Physical Chemistry, vol. 90, no. 7, Mar. 1986, pp. 1445-1448. https://doi.org/10.1021/j100398a045.
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