Journal of the American Chemical Society, volume 141, issue 32, pages 12717-12723
Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol
Hengpan Yang
1
,
Yu Wu
2
,
Guodong Li
2
,
Qing Lin
1
,
Qi Hu
1
,
Qian-Ling Zhang
1
,
Jianhong Liu
1
,
Publication type: Journal Article
Publication date: 2019-07-26
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
Electrocatalytic reduction reaction of CO2 (CO2RR) is an effective way to mitigate energy and environmental issues. However, very limited catalysts are capable of converting CO2 resources into high-value products such as hydrocarbons or alcohols. Herein, we first propose a facile strategy for the large-scale synthesis of isolated Cu decorated through-hole carbon nanofibers (CuSAs/TCNFs). This CuSAs/TCNFs membrane has excellent mechanical properties and can be directly used as cathode for CO2RR, which could generate nearly pure methanol with 44% Faradaic efficiency in liquid phase. The self-supporting and through-hole structure of CuSAs/TCNFs greatly reduces the embedded metal atoms and produces abundant efficient Cu single atoms, which could actually participate in CO2RR, eventually causing -93 mA cm-2 partial current density for C1 products and more than 50 h stability in aqueous solution. According to DFT calculations, Cu single atoms possess a relatively higher binding energy for *CO intermediate. Therefore, *CO could be further reduced to products like methanol, instead of being easily released from the catalyst surface as CO product. This report may benefit the design of efficient and high-yield single-atom catalysts for other electrocatalytic reactions.
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Citations by publishers
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- We do not take into account publications without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
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Yang H. et al. Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol // Journal of the American Chemical Society. 2019. Vol. 141. No. 32. pp. 12717-12723.
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Yang H., Wu Yu., Li G., Lin Q., Hu Q., Zhang Q., Liu J., He C. Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol // Journal of the American Chemical Society. 2019. Vol. 141. No. 32. pp. 12717-12723.
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TY - JOUR
DO - 10.1021/jacs.9b04907
UR - https://doi.org/10.1021/jacs.9b04907
TI - Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol
T2 - Journal of the American Chemical Society
AU - Lin, Qing
AU - Liu, Jianhong
AU - He, Chuanxin
AU - Yang, Hengpan
AU - Wu, Yu
AU - Li, Guodong
AU - Hu, Qi
AU - Zhang, Qian-Ling
PY - 2019
DA - 2019/07/26 00:00:00
PB - American Chemical Society (ACS)
SP - 12717-12723
IS - 32
VL - 141
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2019_Yang,
author = {Qing Lin and Jianhong Liu and Chuanxin He and Hengpan Yang and Yu Wu and Guodong Li and Qi Hu and Qian-Ling Zhang},
title = {Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {jul},
url = {https://doi.org/10.1021/jacs.9b04907},
number = {32},
pages = {12717--12723},
doi = {10.1021/jacs.9b04907}
}
Cite this
MLA
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Yang, Hengpan, et al. “Scalable Production of Efficient Single-Atom Copper Decorated Carbon Membranes for CO2 Electroreduction to Methanol.” Journal of the American Chemical Society, vol. 141, no. 32, Jul. 2019, pp. 12717-12723. https://doi.org/10.1021/jacs.9b04907.