Journal of the American Chemical Society, volume 141, issue 38, pages 14966-14970
Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide.
Halabi Jad Mahmoud
1
,
Ahmed E.
1
,
Catalano Luca
1
,
Karothu Durga
1
,
Rezgui Rachid
1
,
Naumov Pance
1, 2
2
Radcliffe Institute for Advanced Study, Harvard University, 10 Garden Street, Cambridge, Massachusetts 02138, United States
|
Publication type: Journal Article
Publication date: 2019-09-10
Quartile SCImago
Q1
Quartile WOS
Q1
Impact factor: 15
ISSN: 00027863, 15205126
General Chemistry
Catalysis
Biochemistry
Colloid and Surface Chemistry
Abstract
The versatility in mechanical properties and the capability of optical waveguiding of molecular crystals has attracted research on the potential application of these materials in optomechanical transduction. Here, we demonstrate spatial photocontrol over the optical output from slender single crystals of an azo compound, 3',4'-dimethyl-4-(dimethylamino)azobenzene that can be used as crystalline optical waveguide. The position of the free end of a single crystal can be controlled through reversible photoswitching between the trans and cis isomers at the irradiated crystal surface. The passive optical waveguiding capability of the crystal remains unaffected by its deformation induced by exposure to UV light. Moreover, the response time of the material by bending upon irradiation can be thermally regulated to control the positioning of the tip of the crystal. These single-crystal organic actuators with dual (optical and photomechanical) response deliver on the long sought for dynamic all-organic optical elements to be incorporated in microcircuits.
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1 publication, 0.95%
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50
60
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- We do not take into account publications that without a DOI.
- Statistics recalculated only for publications connected to researchers, organizations and labs registered on the platform.
- Statistics recalculated weekly.
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Halabi J. M. et al. Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide. // Journal of the American Chemical Society. 2019. Vol. 141. No. 38. pp. 14966-14970.
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Halabi J. M., Ahmed E., Catalano L., Karothu D., Rezgui R., Naumov P. Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide. // Journal of the American Chemical Society. 2019. Vol. 141. No. 38. pp. 14966-14970.
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TY - JOUR
DO - 10.1021/jacs.9b07645
UR - https://doi.org/10.1021%2Fjacs.9b07645
TI - Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide.
T2 - Journal of the American Chemical Society
AU - Ahmed, E.
AU - Karothu, Durga
AU - Naumov, Pance
AU - Halabi, Jad Mahmoud
AU - Catalano, Luca
AU - Rezgui, Rachid
PY - 2019
DA - 2019/09/10 00:00:00
PB - American Chemical Society (ACS)
SP - 14966-14970
IS - 38
VL - 141
SN - 0002-7863
SN - 1520-5126
ER -
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@article{2019_Halabi,
author = {E. Ahmed and Durga Karothu and Pance Naumov and Jad Mahmoud Halabi and Luca Catalano and Rachid Rezgui},
title = {Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide.},
journal = {Journal of the American Chemical Society},
year = {2019},
volume = {141},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021%2Fjacs.9b07645},
number = {38},
pages = {14966--14970},
doi = {10.1021/jacs.9b07645}
}
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MLA
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Halabi, Jad Mahmoud, et al. “Spatial Photocontrol of the Optical Output from an Organic Crystal Waveguide..” Journal of the American Chemical Society, vol. 141, no. 38, Sep. 2019, pp. 14966-14970. https://doi.org/10.1021%2Fjacs.9b07645.