Hydrogen Adsorption on Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC Metal–Organic Frameworks
Publication type: Journal Article
Publication date: 2013-10-25
scimago Q2
wos Q2
SJR: 0.449
CiteScore: 4.0
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Abstract
This work reports hydrogen adsorption properties of four different metal–organic frameworks (MOFs) namely Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC. Gravimetric hydrogen adsorption measurements are performed over a wide range of temperature (90 K to 298 K) and pressure (0 bar to 100 bar). At the lowest experimental temperature (90 K to 100 K) all the isotherms are saturated and the adsorption capacity is governed by pore volume. On the other hand, at room temperature the isotherms closely follow Henry’s law. Modeling of the excess isotherms is also done. Net adsorption isotherms, which can directly indicate the efficiency of porous adsorbent for storage, are also presented. In terms of volumetric efficiency, Mg-DOBDC MOF exhibits best storage capacity out of all the MOFs considered in this study.
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Total citations:
18
Citations from 2025:
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(5.56%)
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GOST
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Sahu D. et al. Hydrogen Adsorption on Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC Metal–Organic Frameworks // Journal of Chemical & Engineering Data. 2013. Vol. 58. No. 11. pp. 3096-3101.
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Sahu D., Mishra P., Edubilli S., Verma A. K., Gumma S. Hydrogen Adsorption on Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC Metal–Organic Frameworks // Journal of Chemical & Engineering Data. 2013. Vol. 58. No. 11. pp. 3096-3101.
Cite this
RIS
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TY - JOUR
DO - 10.1021/je400546d
UR - https://doi.org/10.1021/je400546d
TI - Hydrogen Adsorption on Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC Metal–Organic Frameworks
T2 - Journal of Chemical & Engineering Data
AU - Sahu, Debjyoti
AU - Mishra, Prashant
AU - Edubilli, Satyannarayana
AU - Verma, Anil Kumar
AU - Gumma, Sasidhar
PY - 2013
DA - 2013/10/25
PB - American Chemical Society (ACS)
SP - 3096-3101
IS - 11
VL - 58
SN - 0021-9568
SN - 1520-5134
ER -
Cite this
BibTex (up to 50 authors)
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@article{2013_Sahu,
author = {Debjyoti Sahu and Prashant Mishra and Satyannarayana Edubilli and Anil Kumar Verma and Sasidhar Gumma},
title = {Hydrogen Adsorption on Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC Metal–Organic Frameworks},
journal = {Journal of Chemical & Engineering Data},
year = {2013},
volume = {58},
publisher = {American Chemical Society (ACS)},
month = {oct},
url = {https://doi.org/10.1021/je400546d},
number = {11},
pages = {3096--3101},
doi = {10.1021/je400546d}
}
Cite this
MLA
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Sahu, Debjyoti, et al. “Hydrogen Adsorption on Zn-BDC, Cr-BDC, Ni-DABCO, and Mg-DOBDC Metal–Organic Frameworks.” Journal of Chemical & Engineering Data, vol. 58, no. 11, Oct. 2013, pp. 3096-3101. https://doi.org/10.1021/je400546d.