Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO
Тип публикации: Journal Article
Дата публикации: 2009-09-11
scimago Q2
wos Q2
БС2
SJR: 0.449
CiteScore: 4
Impact factor: 2.1
ISSN: 00219568, 15205134
General Chemistry
General Chemical Engineering
Краткое описание
Molar conductivities, Λ, of dilute solutions of the ionic liquids 1-butyl-3-methylimidazolium chloride and 1-butyl-3-methylimidazolium tetrafluoroborate in methanol and DMSO were determined as a function of temperature (methanol, T = (273.15 to 313.15) K; DMSO, T = (293.15 to 318.15) K). The data were analyzed with Barthel’s low-concentration chemical model (lcCM) model to obtain the limiting molar conductivities, Λ∞(T), and association constants, KA°(T), of these electrolytes. From Λ∞(T), the Eyring activation enthalpy of charge transport and (where possible) the ion conductivity of the cation, λ∞([bmim]+), were determined.
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Bešter-Rogač M. et al. Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO // Journal of Chemical & Engineering Data. 2009. Vol. 55. No. 5. pp. 1799-1803.
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Bešter-Rogač M., Hunger J., Stoppa A., Buchner R. Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO // Journal of Chemical & Engineering Data. 2009. Vol. 55. No. 5. pp. 1799-1803.
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TY - JOUR
DO - 10.1021/je900531b
UR - https://doi.org/10.1021/je900531b
TI - Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO
T2 - Journal of Chemical & Engineering Data
AU - Bešter-Rogač, Marija
AU - Hunger, Johannes
AU - Stoppa, Alexander
AU - Buchner, Richard
PY - 2009
DA - 2009/09/11
PB - American Chemical Society (ACS)
SP - 1799-1803
IS - 5
VL - 55
SN - 0021-9568
SN - 1520-5134
ER -
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@article{2009_Bešter-Rogač,
author = {Marija Bešter-Rogač and Johannes Hunger and Alexander Stoppa and Richard Buchner},
title = {Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO},
journal = {Journal of Chemical & Engineering Data},
year = {2009},
volume = {55},
publisher = {American Chemical Society (ACS)},
month = {sep},
url = {https://doi.org/10.1021/je900531b},
number = {5},
pages = {1799--1803},
doi = {10.1021/je900531b}
}
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MLA
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Bešter-Rogač, Marija, et al. “Molar Conductivities and Association Constants of 1-Butyl-3-methylimidazolium Chloride and 1-Butyl-3-methylimidazolium Tetrafluoroborate in Methanol and DMSO.” Journal of Chemical & Engineering Data, vol. 55, no. 5, Sep. 2009, pp. 1799-1803. https://doi.org/10.1021/je900531b.